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Information on EC 1.14.14.77 - phenylacetonitrile alpha-monooxygenase

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IUBMB Comments
The enzyme has been characterized from the cyanogenic millipede Chamberlinius hualienensis. Unlike plant enzymes that can catalyse this reaction (EC 1.14.14.44, phenylacetaldehyde oxime monooxygenase), this enzyme cannot act on phenylacetaldehyde oximes. It can accept (4-hydroxyphenyl)acetonitrile, (2-methylphenyl)acetonitrile, and (3-methylphenyl)acetonitrile as substrates at a lower rate.
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The expected taxonomic range for this enzyme is: Chamberlinius hualienensis
Synonyms
CYP3201B1, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
phenylacetonitrile + [reduced NADPH-hemoprotein reductase] + O2 = (R)-mandelonitrile + [oxidized NADPH-hemoprotein reductase] + H2O
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PATHWAY SOURCE
PATHWAYS
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