Information on EC 1.3.1.113 - (4-alkanoyl-5-oxo-2,5-dihydrofuran-3-yl)methyl phosphate reductase
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The expected taxonomic range for this enzyme is: Streptomyces griseus
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(4-alkanoyl-5-oxo-2,5-dihydrofuran-3-yl)methyl phosphate reductase
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a [(3S)-4-alkanoyl-5-oxooxolan-3-yl]methyl phosphate + NADP+ = a (4-alkanoyl-5-oxo-2,5-dihydrofuran-3-yl)methyl phosphate + NADPH + H+
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A-factor gamma-butyrolactone biosynthesis
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IM-2 type gamma-butyrolactones biosynthesis
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[(3S)-4-alkanoyl-5-oxooxolan-3-yl]methyl phosphate:NADP+ oxidoreductase
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butenolide phosphate reductase
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bprA

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gene name
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brenda
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[4-(6-methylheptanoyl)-5-oxo-2,5-dihydrofuran-3-yl]methyl phosphate + NADPH + H+
[(3S)-4-(6-methylheptanoyl)-5-oxooxolan-3-yl]methyl phosphate + NADP+
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additional information
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no activity with NADH
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Kato, J.; Funa, N.; Watanabe, H.; Ohnishi, Y.; Horinouchi, S.
Biosynthesis of gamma-butyrolactone autoregulators that switch on secondary metabolism and morphological development in Streptomyces
Proc. Natl. Acad. Sci. USA
104
2378-2383
2007
Streptomyces griseus
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brenda
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