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Information on EC 1.3.1.123 - 8-oxogeranial reductase

for references in articles please use BRENDA:EC1.3.1.123
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IUBMB Comments
The enzyme, characterized from the plant Antirrhinum majus (snapdragon), is involved in biosynthesis of 7-epi-iridoids such as antirrhinoside. The enzyme catalyses the stereospecific reduction of 8-oxogeranial, forming an unstable product that in the absence of additional cylases undergoes spontaneous cyclization to (-)-cis,trans-nepetalactol. cf. EC 1.3.1.122, (S)-8-oxocitronellyl enol synthase.
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The enzyme appears in viruses and cellular organisms
Synonyms
AmISY, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
(R)-8-oxocitronellyl enol + NADP+ = (6E)-8-oxogeranial + NADPH + H+
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