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IUBMB CommentsInvolved in the interconversion of heteroyohimbine alkaloids in Catharanthus roseus.
The expected taxonomic range for this enzyme is: Catharanthus roseus
Synonyms
dehydrogenase, geissoschizine,
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dehydrogenase, geissoschizine
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geissoschizine + NADP+ = 4,21-didehydrogeissoschizine + NADPH
geissoschizine + NADP+ = 4,21-didehydrogeissoschizine + NADPH
removal of 21alpha-hydrogen takes place from the less hindered site
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geissoschizine + NADP+ = 4,21-didehydrogeissoschizine + NADPH
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geissoschizine:NADP+ 4,21-oxidoreductase
Involved in the interconversion of heteroyohimbine alkaloids in Catharanthus roseus.
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geissoschizine + NADP+
4,21-dehydrogeissoschizine + NADPH
geissoschizine + NADP+
4,21-dehydrogeissoschizine + NADPH
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structurally related indole alkaloids are not dehydrogenated
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geissoschizine + NADP+
4,21-dehydrogeissoschizine + NADPH
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involved in interconversion of heteroyohimbine alkaloids, the enzyme channels geissoschizine by a side reaction into the main pathway
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geissoschizine + NADP+
4,21-dehydrogeissoschizine + NADPH
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involved in interconversion of heteroyohimbine alkaloids, the enzyme channels geissoschizine by a side reaction into the main pathway
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NADP+
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NAD+, FAD or FMN cannot act as cofactors
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brenda
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GS_CATRO
364
0
39517
Swiss-Prot
other Location (Reliability: 3)
FABV_TREDE
Treponema denticola (strain ATCC 35405 / DSM 14222 / CIP 103919 / JCM 8153 / KCTC 15104)
397
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43759
Swiss-Prot
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Pfitzner A.; Stckigt, J.
Partial purification and characterization of geissoschizzine dehydrogenase from suspension cultures of Catharanthus roseus
Phytochemistry
21
1585-1588
1982
Catharanthus roseus
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brenda
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1.3.1.36 geissoschizine dehydrogenase
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