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IUBMB CommentsAs well as 61% longifolene the enzyme gives 15% of alpha-longipinene, 6% longicyclene and traces of other sesquiterpenoids.
The expected taxonomic range for this enzyme is: Pinidae
Synonyms
longifolene synthase,
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(2E,6E)-farnesyl diphosphate = longifolene + diphosphate
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(2E,6E)-farnesyl-diphosphate diphosphate-lyase (longifolene-forming)
As well as 61% longifolene the enzyme gives 15% of alpha-longipinene, 6% longicyclene and traces of other sesquiterpenoids.
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(2E,6E)-farnesyl diphosphate
longifolene + diphosphate
additional information
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(2E,6E)-farnesyl diphosphate
longifolene + diphosphate
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main product
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(2E,6E)-farnesyl diphosphate
longifolene + diphosphate
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main product
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additional information
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longifolene synthase gives besides the main product longifolene (60.6% yield) alpha-longipinene (14.6%), longicyclene (5.9%), (E)-beta-farnesene (3.4%), longiborneol (2.1%), cyclosativene (1.3%), beta-longipinene (1.4%) and other sesquiterpenes (less than 1.4% each)
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additional information
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longifolene synthase gives besides the main product longifolene (60.6% yield) alpha-longipinene (14.6%), longicyclene (5.9%), (E)-beta-farnesene (3.4%), longiborneol (2.1%), cyclosativene (1.3%), beta-longipinene (1.4%) and other sesquiterpenes (less than 1.4% each)
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additional information
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longifolene synthase gives besides the main product longifolene (60.6% yield) alpha-longipinene (14.6%), longicyclene (5.9%), (E)-beta-farnesene (3.4%), longiborneol (2.1%), cyclosativene (1.3%), beta-longipinene (1.4%) and other sesquiterpenes (less than 1.4% each)
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(2E,6E)-farnesyl diphosphate
longifolene + diphosphate
additional information
?
-
(2E,6E)-farnesyl diphosphate
longifolene + diphosphate
-
main product
-
?
(2E,6E)-farnesyl diphosphate
longifolene + diphosphate
-
-
main product
-
?
additional information
?
-
longifolene synthase gives besides the main product longifolene (60.6% yield) alpha-longipinene (14.6%), longicyclene (5.9%), (E)-beta-farnesene (3.4%), longiborneol (2.1%), cyclosativene (1.3%), beta-longipinene (1.4%) and other sesquiterpenes (less than 1.4% each)
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?
additional information
?
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longifolene synthase gives besides the main product longifolene (60.6% yield) alpha-longipinene (14.6%), longicyclene (5.9%), (E)-beta-farnesene (3.4%), longiborneol (2.1%), cyclosativene (1.3%), beta-longipinene (1.4%) and other sesquiterpenes (less than 1.4% each)
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?
additional information
?
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longifolene synthase gives besides the main product longifolene (60.6% yield) alpha-longipinene (14.6%), longicyclene (5.9%), (E)-beta-farnesene (3.4%), longiborneol (2.1%), cyclosativene (1.3%), beta-longipinene (1.4%) and other sesquiterpenes (less than 1.4% each)
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Norway spruce
SwissProt
brenda
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TPSLS_PICAB
578
0
67181
Swiss-Prot
other Location (Reliability: 5)
TPSLS_PICXS
578
0
67054
Swiss-Prot
other Location (Reliability: 5)
A0A6B8N7J0_TAICR
577
0
66885
TrEMBL
other Location (Reliability: 4)
A0A6C0TLK1_TAICR
577
0
66858
TrEMBL
other Location (Reliability: 4)
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Martin, D.M.; Faeldt, J.; Bohlmann, J.
Functional characterization of nine Norway spruce TPS genes and evolution of gymnosperm terpene synthases of the TPS-d subfamily
Plant Physiol.
135
1908-1927
2004
Picea abies (Q675L0), Picea abies
brenda
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4.2.3.58 longifolene synthase
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