Ligand (6aS,11aS)-4-dimethylallyl-3,6a,9-trihydroxypterocarpan

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Basic Ligand Information

Molecular Structure
Picture of (6aS,11aS)-4-dimethylallyl-3,6a,9-trihydroxypterocarpan (click for magnification)
Molecular Formula
BRENDA Name
InChIKey
C20H20O5
(6aS,11aS)-4-dimethylallyl-3,6a,9-trihydroxypterocarpan
NLHMQOCIFRDSNU-VQTJNVASSA-N
Synonyms:
2-(or 4-)dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan, 4-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan

Roles as Enzyme Ligand

In Vivo Product in Enzyme-catalyzed Reactions (1 result)

EC NUMBER
PROVEN IN VIVO REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
2 dimethylallyl diphosphate + 2 (6aS,11aS)-3,6a,9-trihydroxypterocarpan = 2 diphosphate + (6aS,11aS)-2-dimethylallyl-3,6a,9-trihydroxypterocarpan + (6aS,11aS)-4-dimethylallyl-3,6a,9-trihydroxypterocarpan
show the reaction diagram
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Substrate in Enzyme-catalyzed Reactions (1 result)

EC NUMBER
REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
2-(or 4-)dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan + [reduced NADPH-hemoprotein reductase] + O2 = glyceollin + [oxidized NADPH-hemoprotein reductase] + H2O
show the reaction diagram
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Product in Enzyme-catalyzed Reactions (1 result)

EC NUMBER
REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
2 dimethylallyl diphosphate + 2 (6aS,11aS)-3,6a,9-trihydroxypterocarpan = 2 diphosphate + (6aS,11aS)-2-dimethylallyl-3,6a,9-trihydroxypterocarpan + (6aS,11aS)-4-dimethylallyl-3,6a,9-trihydroxypterocarpan
show the reaction diagram
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Enzyme Kinetic Parameters

KM Value (1 result)

EC NUMBER
KM VALUE [MM]
KM VALUE MAXIMUM [MM]
COMMENTARY
LITERATURE
0.002
-
pH 7.5, 20°C, mixture of the two glyceollidin isomers

References & Links

Links to other databases for (6aS,11aS)-4-dimethylallyl-3,6a,9-trihydroxypterocarpan

ChEBI
PubChem
ChEBI
PubChem