Literature summary for 1.10.3.1 extracted from

Mandal, L.; Mandal, S.; Mohanta, S.
Syntheses, crystal structures, magnetochemistry and catechol oxidase activity of a tetracopper(II) compound and a new type of dicopper(II)-based 1D coordination polymer (2017), New J. Chem., 41, 4689-4701 .

No PubMed abstract available

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Crystallization (Commentary)

Crystallization (Comment)	Organism
cluster [CuII4L2(my3-OH)2(NCO)4] 2H2O and one-dimensional coordination polymer [[[CuII2L(my1,1-N3)]2(my1,1-N3)2](my1,3-N3)2]n	synthetic construct

Organism

Organism	UniProt	Comment	Textmining
synthetic construct	-	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
3,5-di-tert-butyl catechol + O2	-	synthetic construct	3,5-di-tert-butyl-o-quinone	-	?

General Information

General Information	Comment	Organism
metabolism	tetracopper(II) cluster [CuII4L2(my3-OH)2(NCO)4] 2H2O and one-dimensional coordination polymer [[[CuII2L(my1,1-N3)]2(my1,1-N3)2](my1,3-N3)2]n derived from a Schiff base are functional models for catechol oxidase activity in N,N-dimethylformamide (DMF) and acetonitrile, with Kcat values around 15 per h for cluster [CuII4L2(m3-OH)2(NCO)4] 2H2O and 13 per h for polymer [[[CuII2L(m1,1-N3)]2(m1,1-N3)2](m1,3-N3)2]n	synthetic construct

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Release 2023.1 (January 2023)