Cloned (Comment) | Organism |
---|---|
recombinant enzyme | Pisum sativum |
Protein Variants | Comment | Organism |
---|---|---|
W41A | the mutation enables the efficient conversion of recombinant enzyme into a stereoselective oxidizing agent for sulfides | Pisum sativum |
Localization | Comment | Organism | GeneOntology No. | Textmining |
---|---|---|---|---|
cytosol | - |
Pisum sativum | 5829 | - |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
Pisum sativum | - |
pea | - |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
ethyl phenyl sulfide + H2O2 | - |
Pisum sativum | ? + H2O | - |
? | |
isopropyl phenyl sulfide + H2O2 | - |
Pisum sativum | ? + H2O | - |
? | |
L-ascorbate + H2O2 | - |
Pisum sativum | dehydroascorbate + H2O | - |
? | |
methyl naphthalene sulfide + H2O2 | - |
Pisum sativum | ? + H2O | - |
? | |
methyl phenyl sulfide + H2O2 | - |
Pisum sativum | ? + H2O | - |
? | |
additional information | experimental and modelled enantiomeric ratios R: S for oxidation of thioethers by recombinant enzyme and mutant Trp-41-Ala | Pisum sativum | ? | - |
? | |
n-propyl phenyl sulfide + H2O2 | - |
Pisum sativum | ? + H2O | - |
? | |
p-chlorophenyl methyl sulfide + H2O2 | - |
Pisum sativum | ? + H2O | - |
? | |
p-cresol + cumene-hydroperoxide | - |
Pisum sativum | 4a,9b-dihydro-8,9b-dimethyl-3(4H)-dibenzofuranone + 2,2'-dihydroxy-5,5'-dimethylbiphenyl + 1,1-dimethylbenzylalcohol + bis-(1-methyl-1-phenylethyl)peroxide | the formation of bis-(1-methyl-1-phenylethyl)peroxide derives from the reaction of 1,1-dimethylbenzylalcohol with either p-cresol or 2,2'-dihydroxy-5,5'-dimethylbiphenyl | ? | |
p-cresol + H2O2 | - |
Pisum sativum | 4a,9b-dihydro-8,9b-dimethyl-3(4H)-dibenzofuranone + 2,2'-dihydroxy-5,5'-dimethylbiphenyl + H2O | these products, which are derived from reactions of the p-methylphenoxy radical, itself form as a direct result of single-electron oxidation of p-cresol by the enzyme, can be accommodated from the known chemistry of the radical products, the product ratio 4alpha,9beta-dihydro-8,9beta-dimethyl-3(4H)-dibenzofuranone: 2,2'-dihydroxy-5,5'-dimethylbiphenyl is found to depend on enzyme concentration | ? | |
p-nitrophenyl methyl sulfide + H2O2 | - |
Pisum sativum | ? + H2O | - |
? |