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Literature summary for 1.14.13.187 extracted from

  • Al-Mestarihi, A.; Romo, A.; Liu, H.; Bachmann, B.
    Nitrososynthase-triggered oxidative carbon-carbon bond cleavage in baumycin biosynthesis (2013), J. Am. Chem. Soc., 135, 11457-11460.
    View publication on PubMedView publication on EuropePMC

Organism

Organism UniProt Comment Textmining
Streptomyces peucetius O33706
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
TDP-L-epi-vancosamine + 2 NADPH + 2 H+ + 2 O2
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Streptomyces peucetius ? + 2 NADP+ + 3 H2O the enzyme catalyzes oxidation of TDP-L-epi-vancosamine to its vicinal hydroxy nitroso congener triggers C-C bond cleavage. The overall rearrangement of the hydroxy nitroso sugar to the aldehyde-oxime product is formally that of a retro oxime-aldol transformation ?

Synonyms

Synonyms Comment Organism
DnmZ
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Streptomyces peucetius