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Literature summary for 1.14.13.22 extracted from

  • Abril, O.; Ryerson, C.C.; Walsh, C.; Whitesides, G.M.
    Enzymatic Baeyer-Villiger type oxidations of ketones catalyzed by cyclohexanone oxygenase (1989), Bioorg. Chem., 17, 41-52.
No PubMed abstract available
Search for more literature for 1.14.13.22

Organism

Organism UniProt Comment Textmining
Acinetobacter sp.
-
 NCIB 9871
-

Reaction

Reaction Comment Organism Reaction ID
cyclohexanone + NADPH + H+ + O2 = hexano-6-lactone + NADP+ + H2O general mechanistic scheme Acinetobacter sp.
a
cyclohexanone + NADPH + H+ + O2 = hexano-6-lactone + NADP+ + H2O regioselectivity Acinetobacter sp.
a

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(+)-camphor + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?
(+)-dihydrocarvone + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?
2-norbornanone + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?
2-phenylcyclohexanone + NADPH + O2 slight Acinetobacter sp. 1-oxa-2-oxo-3-phenylcycloheptane + NADP+ + H2O
-
 ?
4-tert-butylcyclohexanone + NADPH + O2 slight Acinetobacter sp. 1-oxa-2-oxo-5-tert-butylcycloheptane + NADP+ + H2O
-
 ?
cyclohexan-1,4-dione + NADPH + O2
-
 Acinetobacter sp. 1-oxa-2,5-dioxo-cycloheptane + NADP+ + H2O
-
 ?
cyclohexanone + NADPH + O2
-
 Acinetobacter sp. 6-hexanolide + NADP+ + H2O
-
 ?
D-fenchone + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?
syn-7-benzyloxymethyl-2-norbonen-5-one + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?

Cofactor

Cofactor Comment Organism Structure
FAD
-
 Acinetobacter sp.
NADPH electron donor Acinetobacter sp.