Natural Substrates | Organism | Comment (Nat. Sub.) | Natural Products | Comment (Nat. Pro.) | Rev. | Reac. |
---|---|---|---|---|---|---|
styrene + FADH2 + O2 | Pseudomonas sp. | - |
(S)-2-phenyloxirane + FAD + H2O | - |
? | |
styrene + FADH2 + O2 | Pseudomonas sp. VLB120 | - |
(S)-2-phenyloxirane + FAD + H2O | - |
? |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
Pseudomonas sp. | - |
- |
- |
Pseudomonas sp. VLB120 | - |
- |
- |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
additional information | feasibility of direct electrochemical regeneration of a flavin-dependent monooxygenase for catalysis. Driven only by electrical power, optically pure epoxides are synthesized from corresponding vinyl aromatic compounds. The complicated native enzyme system consisting of three enzymes (StyA, StyB, and an NADH regenerating enzyme) and two cofactors (NADH and FAD) is minimized to the oxygenase component and its flavin prosthetic group | Pseudomonas sp. | ? | - |
? | |
additional information | feasibility of direct electrochemical regeneration of a flavin-dependent monooxygenase for catalysis. Driven only by electrical power, optically pure epoxides are synthesized from corresponding vinyl aromatic compounds. The complicated native enzyme system consisting of three enzymes (StyA, StyB, and an NADH regenerating enzyme) and two cofactors (NADH and FAD) is minimized to the oxygenase component and its flavin prosthetic group | Pseudomonas sp. VLB120 | ? | - |
? | |
styrene + FADH2 + O2 | - |
Pseudomonas sp. | (S)-2-phenyloxirane + FAD + H2O | - |
? | |
styrene + FADH2 + O2 | production of (S)-styrene oxide with 98.5% enantiomeric excess. Direct electrochemical regeneration of FADH2 to substitute for the complex native regeneration cycle including StyB and NADH | Pseudomonas sp. | (S)-2-phenyloxirane + FAD + H2O | - |
? | |
styrene + FADH2 + O2 | - |
Pseudomonas sp. VLB120 | (S)-2-phenyloxirane + FAD + H2O | - |
? | |
styrene + FADH2 + O2 | production of (S)-styrene oxide with 98.5% enantiomeric excess. Direct electrochemical regeneration of FADH2 to substitute for the complex native regeneration cycle including StyB and NADH | Pseudomonas sp. VLB120 | (S)-2-phenyloxirane + FAD + H2O | - |
? |
Synonyms | Comment | Organism |
---|---|---|
StyA | - |
Pseudomonas sp. |
Cofactor | Comment | Organism | Structure |
---|---|---|---|
FADH2 | direct electrochemical regeneration of FADH2 to substitute for the complex native regeneration cycle including StyB and NADH | Pseudomonas sp. |