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Literature summary for 3.1.1.3 extracted from
- Selective esterification of phthalic acids in two ionic liquids at high temperatures using a thermostable lipase of Bacillus thermocatenulatus: A comparative study (2008), J. Mol. Catal. B, 52-53, 162-167.
No PubMed abstract available
Activating Compound
| Activating Compound | Comment | Organism | Structure |
|---|---|---|---|
| 2-butanol | 2-butanol enhances lipase activity | Geobacillus thermocatenulatus |  |
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| Geobacillus thermocatenulatus | - |
- |
- |
Substrates and Products (Substrate)
| Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| isophthalate + 2-butanol | - |
Geobacillus thermocatenulatus | isophthalic acid mono(1-methylpropyl)ester + isophthalic acid di(1-methylpropyl)ester + H2O | the yield is 34% monoester and 46% diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer | ? | |
| isophthalate + cyclohexanol | - |
Geobacillus thermocatenulatus | isophthalic acid monocyclohexyl ester + H2O | the yield is 7% monoester, no formation of diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer | ? | |
| isophthalate + cyclopentanol | - |
Geobacillus thermocatenulatus | isophthalic acid monocyclopentyl ester + H2O | the yield is 5% monoester, no formation of diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer | ? | |
| isophthalate + ethanol | - |
Geobacillus thermocatenulatus | isophthalic acid monoethyl ester + isophthalic acid diethyl ester + H2O | the yield is 74% monoester and no diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer and 38% monoester and 24% diester in 1-butyl-3-methyl imidazolium hexafluorophosphate buffer respectively | ? | |
| isophthalate + n-butanol | - |
Geobacillus thermocatenulatus | isophthalic acid monobutyl ester + H2O | the yield is 14% for the monoester, no formation of diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer | ? | |
| phthalate + ethanol | - |
Geobacillus thermocatenulatus | phthalic acid monoethyl ester + phthalic acid diethyl ester + H2O | the yield is 49% monoester and 30% diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer and 67% monoester and 33% diester in 1-butyl-3-methyl imidazolium hexafluorophosphate buffer respectively | ? | |
| terephthalate + ethanol | - |
Geobacillus thermocatenulatus | terephthalic acid monoethyl ester + terephthalic acid diethyl ester + H2O | the yield is 44% monoester and no diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer and 39% monoester and 51% diester in 1-butyl-3-methyl imidazolium hexafluorophosphate buffer respectively | ? | |
Synonyms
| Synonyms | Comment | Organism |
|---|---|---|
| lipase | - |
Geobacillus thermocatenulatus |
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