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Literature summary for 4.2.3.16 extracted from

  • Rajaonarivony, J.I.M.; Gershenzon, J.; Miyazaki, J.; Croteau, R.
    Evidence for an essential histidine residue in 4S-limonene synthase and other terpene cyclases (1992), Arch. Biochem. Biophys., 299, 77-82.
    View publication on PubMed

Inhibitors

Inhibitors Comment Organism Structure
diethyl dicarbonate reversible with hydroxylamine, pretreatment with geranyl diphosphate and MnCl2 prevents inhibition Mentha sp.
linalyl sulfonium ion
-
Mentha sp.
p-hydroxymercuribenzoate
-
Mentha sp.

Metals/Ions

Metals/Ions Comment Organism Structure
Mn2+ required Mentha sp.

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
geranyl diphosphate Mentha sp.
-
(-)-(4S)-limonene + diphosphate
-
?

Organism

Organism UniProt Comment Textmining
Mentha sp.
-
M. x piperita
-

Source Tissue

Source Tissue Comment Organism Textmining
leaf
-
Mentha sp.
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
geranyl diphosphate
-
Mentha sp. (-)-(4S)-limonene + diphosphate
-
?
geranyl diphosphate (3S)-linalyl diphosphate as intermediate Mentha sp. (-)-(4S)-limonene + diphosphate
-
?