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Literature summary extracted from

  • Raybuck, S.A.; Bastian, N.R.; Zydowsky, L.D.; Kobayashi, K.; Floss, H.G.; Orme-Johnson, W.H.; Walsh, C.T.
    Nickel-containing CO dehydrogenase catalyzes reversible decarbonylation of acetyl-CoA with retention of stereochemistry at the methyl group (1987), J. Am. Chem. Soc., 109, 3171-3173.
No PubMed abstract available

Metals/Ions

EC Number Metals/Ions Comment Organism Structure
1.2.7.4 Nickel both CO and CoASH bind near the nickel site, nickel may therefore be the active metal center for C-C bond formation Moorella thermoacetica

Organism

EC Number Organism UniProt Comment Textmining
1.2.7.4 Moorella thermoacetica
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Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.2.7.4 CO + H2O + methyl viologen catalyzes reversible decarbonylation of acetyl-CoA with retention of stereochemistry at the methyl group Moorella thermoacetica CO2 + reduced methyl viologen
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