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Literature summary extracted from

  • Crout, D.H.G.; Littlechild, J.; Mitchell, M.B.; Morrey, S.M.
    Stereochemistry of the decarboxylation of alpha-acetolactate (2-hydroxy-2-methyl-3-oxobutanoate) by the acetolactate decarboxylase of Klebsiella aerogenes (1984), J. Chem. Soc. Perkin Trans. I, 1984, 2271-2276.
No PubMed abstract available

Organism

EC Number Organism UniProt Comment Textmining
4.1.1.5 Klebsiella aerogenes
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Reaction

EC Number Reaction Comment Organism Reaction ID
4.1.1.5 (2S)-2-hydroxy-2-methyl-3-oxobutanoate = (3R)-3-hydroxybutan-2-one + CO2 the carboxy group of alpha-acetolactate is replaced regiospecifically by hydrogen. This process takes place with overall inversion of configuration Klebsiella aerogenes

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
4.1.1.5 2-Hydroxy-2-methyl-3-oxobutanoate
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Klebsiella aerogenes (R)-3-Hydroxybutan-2-one + CO2
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