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Literature summary extracted from

  • Sanfilippo, C.; Nicolosi, G.
    Catalytic behavior of chloroperoxidase from Caldariomyces fumago in the oxidation of cyclic conjugated dienes (2002), Tetrahedron, 13, 1889-1892.
No PubMed abstract available

Organism

EC Number Organism UniProt Comment Textmining
1.11.1.10 Leptoxyphium fumago
-
-
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.11.1.10 (1R,2S)-cyclohexa-3,5-diene-1,2-diyl diacetate + tert-butyl hydroperoxide
-
 Leptoxyphium fumago (1S,2S,3S,6S)-7-oxabicyclo[4.1.0]hept-4-ene-2,3-diyl diacetate + (1R,2S,5R,6S)-5,6-dihydroxycyclohex-3-ene-1,2-diyl diacetate + ?
-
 ?
1.11.1.10 (5R,6S)-5,6-dimethoxycyclohexa-1,3-diene + tert-butyl hydroperoxide
-
 Leptoxyphium fumago (1S,4S,5S,6S)-4,5-dimethoxy-7-oxabicyclo[4.1.0]hept-2-ene + ?
-
 ?
1.11.1.10 1,3-cycloheptadiene + tert-butyl hydroperoxide
-
 Leptoxyphium fumago (1R,3R)-cyclohept-3-ene-1,2-diol + (1R,4S)cyclohept-2-ene-1,4-diol + (1R,4R)-cyclohept-2-ene-1,4-diol + ?
-
 ?
1.11.1.10 1,3-cyclooctadiene + tert-butyl hydroperoxide
-
 Leptoxyphium fumago cycloocta-1,4-dien-1-yl hydroperoxide + cycloocta-2,4-dien-1-ol + ? main product is cycloocta-1,4-dien-1-yl hydroperoxide, formation of small amounts of cycloocta-2,4-dien-1-ol ?
1.11.1.10 cis-cyclohexa-3,5-diene-1,2-diol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago (1R,2S,3S,4S)-cyclohex-5-ene-1,2,3,4-tetrol + ? + traces of (1R,2S,3S,6S)-7-oxabicyclo[4.1.0]hept-4-ene-2,3-diol ?

Synonyms

EC Number Synonyms Comment Organism
1.11.1.10 chloroperoxidase
-
 Leptoxyphium fumago
1.11.1.10 CPO
-
 Leptoxyphium fumago