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Literature summary extracted from

  • Colonna, S.; Pironti, V.; Carrea, G.; Pasta, P.; Zambianchi, F.
    Oxidation of secondary amines by molecular oxygen and cyclohexanone monooxygenase (2004), Tetrahedron, 60, 569-575.
No PubMed abstract available

Application

EC Number Application Comment Organism
1.14.13.22 synthesis manufacturing of fine chemicals Acinetobacter calcoaceticus

Molecular Weight [Da]

EC Number Molecular Weight [Da] Molecular Weight Maximum [Da] Comment Organism
1.14.13.22 60000
-
-
 Acinetobacter calcoaceticus

Natural Substrates/ Products (Substrates)

EC Number Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
1.14.13.22 cyclohexanone + NADPH + O2 Acinetobacter calcoaceticus
-
 epsilon-caprolactone + NADP+ + H2O
-
 ?
1.14.13.22 cyclohexanone + NADPH + O2 Acinetobacter calcoaceticus NCIMB 9871
-
 epsilon-caprolactone + NADP+ + H2O
-
 ?

Organism

EC Number Organism UniProt Comment Textmining
1.14.13.22 Acinetobacter calcoaceticus
-
 NCIMB 9871
-
1.14.13.22 Acinetobacter calcoaceticus NCIMB 9871
-
 NCIMB 9871
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.14.13.22 cyclohexanone + NADPH + O2
-
 Acinetobacter calcoaceticus epsilon-caprolactone + NADP+ + H2O
-
 ?
1.14.13.22 cyclohexanone + NADPH + O2
-
 Acinetobacter calcoaceticus NCIMB 9871 epsilon-caprolactone + NADP+ + H2O
-
 ?
1.14.13.22 cyclohexanone + NADPH + O2
-
 Acinetobacter calcoaceticus hexano-6-lactone + NADP+ + H2O
-
 ?
1.14.13.22 cyclohexanone + NADPH + O2
-
 Acinetobacter calcoaceticus NCIMB 9871 hexano-6-lactone + NADP+ + H2O
-
 ?
1.14.13.22 additional information also catalyze the oxidation of several more secondary amines Acinetobacter calcoaceticus ?
-
 ?
1.14.13.22 additional information also catalyze the oxidation of several more secondary amines Acinetobacter calcoaceticus NCIMB 9871 ?
-
 ?
1.14.13.22 N-methylbenzylamine + NADPH + O2
-
 Acinetobacter calcoaceticus N-benzyl-N-methylhydroxylamine + NADP+ + H2O
-
 ?
1.14.13.22 N-methylbenzylamine + NADPH + O2
-
 Acinetobacter calcoaceticus NCIMB 9871 N-benzyl-N-methylhydroxylamine + NADP+ + H2O
-
 ?

Subunits

EC Number Subunits Comment Organism
1.14.13.22 monomer 1 * 60000 Acinetobacter calcoaceticus

Synonyms

EC Number Synonyms Comment Organism
1.14.13.22 cyclohexanone:NADPH:oxygen oxidoreductase (lactone-forming)
-
 Acinetobacter calcoaceticus

Cofactor

EC Number Cofactor Comment Organism Structure
1.14.13.22 FAD one FAD non-covalently bound to one enzyme molecule Acinetobacter calcoaceticus
1.14.13.22 NADPH
-
 Acinetobacter calcoaceticus