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Literature summary extracted from

  • Kluger, R.; Ikeda, G.; Hu, Q.; Cao, P.; Drewry, J.
    Accelerating unimolecular decarboxylation by preassociated acid catalysis in thiamin-derived intermediates: implicating Bronsted acids as carbanion traps in enzymes (2006), J. Am. Chem. Soc., 128, 15856-15864.
    View publication on PubMed

Organism

EC Number Organism UniProt Comment Textmining
4.1.1.7 Pseudomonas putida
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-
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Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
4.1.1.7 benzoylformate
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Pseudomonas putida benzaldehyde + CO2
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?

Cofactor

EC Number Cofactor Comment Organism Structure
4.1.1.7 thiamine diphosphate the enzyme avoids formation of a benzoyl anion by addition of enzyme-bound thiamine diphosphate to the carbonyl group of benzoylformate, producing enzyme-bound 2-(2-mandelyl)thiamine diphosphate Pseudomonas putida