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Literature summary extracted from

  • Chiang, M.H.; Liu, Y.C.; Yang, S.T.; Lee, G.H.
    Biomimetic model featuring the NH proton and bridging hydride related to a proposed intermediate in enzymatic H(2) production by Fe-only hydrogenase (2009), Inorg. Chem., 48, 7604-7612.
    View publication on PubMed

Metals/Ions

EC Number Metals/Ions Comment Organism Structure
1.12.99.6 Fe iron azadithiolate phosphine-substituted complex and its protonated species featuring the NH proton and/or bridging Fe hydride, [Fe2(micro-S(CH2)2NnPr(H)m(CH2)2S)(micro-H)n(CO)4(PMe3)2]2 (2m+2n)+, mimic the active site of Fe-only hydrogenase. The ability to accept protons for the aza nitrogen and the Fe sites is essential for the enzymatic H2 production at the mild potential synthetic construct

Organism

EC Number Organism UniProt Comment Textmining
1.12.99.6 synthetic construct
-
-
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.12.99.6 H2 + oxidized acceptor
-
synthetic construct H+ + reduced acceptor
-
?

Synonyms

EC Number Synonyms Comment Organism
1.12.99.6 Fe-only hydrogenase
-
synthetic construct