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Literature summary extracted from
- Linolenate 9R-dioxygenase and allene oxide synthase activities of Lasiodiplodia theobromae (2012), Lipids, 47, 65-73.
Localization
| EC Number | Localization | Comment | Organism | GeneOntology No. | Textmining |
|---|---|---|---|---|---|
| 1.13.11.B6 | microsome | - |
Lasiodiplodia theobromae | - |
- |
Natural Substrates/ Products (Substrates)
| EC Number | Natural Substrates | Organism | Comment (Nat. Sub.) | Natural Products | Comment (Nat. Pro.) | Rev. | Reac. |
|---|---|---|---|---|---|---|---|
| 1.13.11.B6 | (9Z,12Z)-octadeca-9,12-dienoic acid + O2 | Lasiodiplodia theobromae | i.e. linoleic acid | (12Z)-9-hydroxy-10-oxo-12-octadecenoic acid | the alpha-ketol is the main metabolite formed from (9R)-hydroperoxyoctadecadienoic acid | ? |  |
| 1.13.11.B6 | (9Z,12Z)-octadeca-9,12-dienoic acid + O2 | Lasiodiplodia theobromae 2334 | i.e. linoleic acid | (12Z)-9-hydroxy-10-oxo-12-octadecenoic acid | the alpha-ketol is the main metabolite formed from (9R)-hydroperoxyoctadecadienoic acid | ? | |
| 1.13.11.B6 | (9Z,12Z)-octadeca-9,12-dienoic acid + O2 | Lasiodiplodia theobromae CBS 117454 | i.e. linoleic acid | (12Z)-9-hydroxy-10-oxo-12-octadecenoic acid | the alpha-ketol is the main metabolite formed from (9R)-hydroperoxyoctadecadienoic acid | ? | |
| 1.13.11.B6 | (9Z,12Z)-octadeca-9,12-dienoic acid + O2 | Lasiodiplodia theobromae CBS 122127 | i.e. linoleic acid | (12Z)-9-hydroxy-10-oxo-12-octadecenoic acid | the alpha-ketol is the main metabolite formed from (9R)-hydroperoxyoctadecadienoic acid | ? | |
| 1.13.11.B6 | (9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + O2 | Lasiodiplodia theobromae | i.e. alpha-linoleic acid | (9R,10E,12Z,15Z)-9-hydroperoxyoctadeca-10,12,15-trienoic acid + (9Z,12Z,15Z)-9-hydroxy-10-oxooctadeca-12,15-dienoic acid | - |
? | |
| 1.13.11.B6 | (9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + O2 | Lasiodiplodia theobromae 2334 | i.e. alpha-linoleic acid | (9R,10E,12Z,15Z)-9-hydroperoxyoctadeca-10,12,15-trienoic acid + (9Z,12Z,15Z)-9-hydroxy-10-oxooctadeca-12,15-dienoic acid | - |
? | |
| 1.13.11.B6 | (9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + O2 | Lasiodiplodia theobromae CBS 117454 | i.e. alpha-linoleic acid | (9R,10E,12Z,15Z)-9-hydroperoxyoctadeca-10,12,15-trienoic acid + (9Z,12Z,15Z)-9-hydroxy-10-oxooctadeca-12,15-dienoic acid | - |
? | |
| 1.13.11.B6 | (9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + O2 | Lasiodiplodia theobromae CBS 122127 | i.e. alpha-linoleic acid | (9R,10E,12Z,15Z)-9-hydroperoxyoctadeca-10,12,15-trienoic acid + (9Z,12Z,15Z)-9-hydroxy-10-oxooctadeca-12,15-dienoic acid | - |
? | |
| 1.13.11.B6 | all-cis-9,12,15-octadecatrienoic acid + O2 | Lasiodiplodia theobromae | i.e. alpha-linoleic acid | (9R)-hydroperoxy-(10E,12Z,15Z)-octadecatrienoic acid + 9-hydroxy-10-oxo-(12Z,15Z)-octadecadienoic acid | - |
? | |
| 1.13.11.B6 | all-cis-9,12,15-octadecatrienoic acid + O2 | Lasiodiplodia theobromae 2334 | i.e. alpha-linoleic acid | (9R)-hydroperoxy-(10E,12Z,15Z)-octadecatrienoic acid + 9-hydroxy-10-oxo-(12Z,15Z)-octadecadienoic acid | - |
? | |
| 1.13.11.B6 | all-cis-9,12,15-octadecatrienoic acid + O2 | Lasiodiplodia theobromae CBS 117454 | i.e. alpha-linoleic acid | (9R)-hydroperoxy-(10E,12Z,15Z)-octadecatrienoic acid + 9-hydroxy-10-oxo-(12Z,15Z)-octadecadienoic acid | - |
? | |
| 1.13.11.B6 | all-cis-9,12,15-octadecatrienoic acid + O2 | Lasiodiplodia theobromae CBS 122127 | i.e. alpha-linoleic acid | (9R)-hydroperoxy-(10E,12Z,15Z)-octadecatrienoic acid + 9-hydroxy-10-oxo-(12Z,15Z)-octadecadienoic acid | - |
? | |
| 1.13.11.B6 | all-cis-9,12-octadecadienoic acid + O2 | Lasiodiplodia theobromae | i.e. linoleic acid | 9-hydroxy-10-oxo-12Z-octadecenoic acid | the alpha-ketol is the main metabolite formed from 9R-hydroperoxyoctadecadienoic acid | ? | |
| 4.2.1.92 | (9R)-hydroperoxy-(10E,12Z,15Z)-octadecatrienoic acid | Lasiodiplodia theobromae | - |
9-hydroxy-10-oxo-(12Z,15Z)-octadecadienoic acid | - |
? | |
| 4.2.1.92 | (9R)-hydroperoxy-(10E,12Z,15Z)-octadecatrienoic acid | Lasiodiplodia theobromae 2334 | - |
9-hydroxy-10-oxo-(12Z,15Z)-octadecadienoic acid | - |
? | |
| 4.2.1.92 | (9R)-hydroperoxy-(10E,12Z,15Z)-octadecatrienoic acid | Lasiodiplodia theobromae CBS 117454 | - |
9-hydroxy-10-oxo-(12Z,15Z)-octadecadienoic acid | - |
? | |
| 4.2.1.92 | (9R)-hydroperoxy-(10E,12Z,15Z)-octadecatrienoic acid | Lasiodiplodia theobromae CBS 122127 | - |
9-hydroxy-10-oxo-(12Z,15Z)-octadecadienoic acid | - |
? | |
Organism
| EC Number | Organism | UniProt | Comment | Textmining |
|---|---|---|---|---|
| 1.13.11.B6 | Lasiodiplodia theobromae | - |
- |
- |
| 1.13.11.B6 | Lasiodiplodia theobromae 2334 | - |
- |
- |
| 1.13.11.B6 | Lasiodiplodia theobromae CBS 117454 | - |
- |
- |
| 1.13.11.B6 | Lasiodiplodia theobromae CBS 122127 | - |
- |
- |
| 4.2.1.92 | Lasiodiplodia theobromae | - |
i.e. Botryodiplodia theobromae, no activity in strain CBS 122127 | - |
| 4.2.1.92 | Lasiodiplodia theobromae 2334 | - |
i.e. Botryodiplodia theobromae, no activity in strain CBS 122127 | - |
Source Tissue
| EC Number | Source Tissue | Comment | Organism | Textmining |
|---|---|---|---|---|
| 1.13.11.B6 | mycelium | - |
Lasiodiplodia theobromae | - |
| 4.2.1.92 | mycelium | - |
Lasiodiplodia theobromae | - |
Substrates and Products (Substrate)
| EC Number | Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|---|
| 1.13.11.B6 | (9Z,12Z)-octadeca-9,12-dienoic acid + O2 | i.e. linoleic acid | Lasiodiplodia theobromae | (12Z)-9-hydroxy-10-oxo-12-octadecenoic acid | the alpha-ketol is the main metabolite formed from (9R)-hydroperoxyoctadecadienoic acid | ? | |
| 1.13.11.B6 | (9Z,12Z)-octadeca-9,12-dienoic acid + O2 | i.e. linoleic acid | Lasiodiplodia theobromae 2334 | (12Z)-9-hydroxy-10-oxo-12-octadecenoic acid | the alpha-ketol is the main metabolite formed from (9R)-hydroperoxyoctadecadienoic acid | ? | |
| 1.13.11.B6 | (9Z,12Z)-octadeca-9,12-dienoic acid + O2 | i.e. linoleic acid | Lasiodiplodia theobromae CBS 117454 | (12Z)-9-hydroxy-10-oxo-12-octadecenoic acid | the alpha-ketol is the main metabolite formed from (9R)-hydroperoxyoctadecadienoic acid | ? | |
| 1.13.11.B6 | (9Z,12Z)-octadeca-9,12-dienoic acid + O2 | i.e. linoleic acid | Lasiodiplodia theobromae CBS 122127 | (12Z)-9-hydroxy-10-oxo-12-octadecenoic acid | the alpha-ketol is the main metabolite formed from (9R)-hydroperoxyoctadecadienoic acid | ? | |
| 1.13.11.B6 | (9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + O2 | i.e. alpha-linoleic acid | Lasiodiplodia theobromae | (9R,10E,12Z,15Z)-9-hydroperoxyoctadeca-10,12,15-trienoic acid + (9Z,12Z,15Z)-9-hydroxy-10-oxooctadeca-12,15-dienoic acid | - |
? | |
| 1.13.11.B6 | (9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + O2 | i.e. alpha-linoleic acid | Lasiodiplodia theobromae 2334 | (9R,10E,12Z,15Z)-9-hydroperoxyoctadeca-10,12,15-trienoic acid + (9Z,12Z,15Z)-9-hydroxy-10-oxooctadeca-12,15-dienoic acid | - |
? | |
| 1.13.11.B6 | (9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + O2 | i.e. alpha-linoleic acid | Lasiodiplodia theobromae CBS 117454 | (9R,10E,12Z,15Z)-9-hydroperoxyoctadeca-10,12,15-trienoic acid + (9Z,12Z,15Z)-9-hydroxy-10-oxooctadeca-12,15-dienoic acid | - |
? | |
| 1.13.11.B6 | (9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + O2 | i.e. alpha-linoleic acid | Lasiodiplodia theobromae CBS 122127 | (9R,10E,12Z,15Z)-9-hydroperoxyoctadeca-10,12,15-trienoic acid + (9Z,12Z,15Z)-9-hydroxy-10-oxooctadeca-12,15-dienoic acid | - |
? | |
| 1.13.11.B6 | all-cis-9,12,15-octadecatrienoic acid + O2 | i.e. alpha-linoleic acid | Lasiodiplodia theobromae | (9R)-hydroperoxy-(10E,12Z,15Z)-octadecatrienoic acid + 9-hydroxy-10-oxo-(12Z,15Z)-octadecadienoic acid | - |
? | |
| 1.13.11.B6 | all-cis-9,12,15-octadecatrienoic acid + O2 | i.e. alpha-linoleic acid | Lasiodiplodia theobromae 2334 | (9R)-hydroperoxy-(10E,12Z,15Z)-octadecatrienoic acid + 9-hydroxy-10-oxo-(12Z,15Z)-octadecadienoic acid | - |
? | |
| 1.13.11.B6 | all-cis-9,12,15-octadecatrienoic acid + O2 | i.e. alpha-linoleic acid | Lasiodiplodia theobromae CBS 117454 | (9R)-hydroperoxy-(10E,12Z,15Z)-octadecatrienoic acid + 9-hydroxy-10-oxo-(12Z,15Z)-octadecadienoic acid | - |
? | |
| 1.13.11.B6 | all-cis-9,12,15-octadecatrienoic acid + O2 | i.e. alpha-linoleic acid | Lasiodiplodia theobromae CBS 122127 | (9R)-hydroperoxy-(10E,12Z,15Z)-octadecatrienoic acid + 9-hydroxy-10-oxo-(12Z,15Z)-octadecadienoic acid | - |
? | |
| 1.13.11.B6 | all-cis-9,12-octadecadienoic acid + O2 | i.e. linoleic acid | Lasiodiplodia theobromae | 9-hydroxy-10-oxo-12Z-octadecenoic acid | the alpha-ketol is the main metabolite formed from 9R-hydroperoxyoctadecadienoic acid | ? | |
| 1.13.11.B6 | additional information | the putative 9R-dioxygenase catalyzes stereospecific removal of the 11R hydrogen followed by suprafacial attack of dioxygen at C-9 | Lasiodiplodia theobromae | ? | - |
? | |
| 1.13.11.B6 | additional information | the putative 9R-dioxygenase catalyzes stereospecific removal of the 11R hydrogen followed by suprafacial attack of dioxygen at C-9 | Lasiodiplodia theobromae 2334 | ? | - |
? | |
| 1.13.11.B6 | additional information | the putative 9R-dioxygenase catalyzes stereospecific removal of the 11R hydrogen followed by suprafacial attack of dioxygen at C-9 | Lasiodiplodia theobromae CBS 117454 | ? | - |
? | |
| 1.13.11.B6 | additional information | the putative 9R-dioxygenase catalyzes stereospecific removal of the 11R hydrogen followed by suprafacial attack of dioxygen at C-9 | Lasiodiplodia theobromae CBS 122127 | ? | - |
? | |
| 4.2.1.92 | (9R)-hydroperoxy-(10E,12Z,15Z)-octadecatrienoic acid | - |
Lasiodiplodia theobromae | 9-hydroxy-10-oxo-(12Z,15Z)-octadecadienoic acid | - |
? | |
| 4.2.1.92 | (9R)-hydroperoxy-(10E,12Z,15Z)-octadecatrienoic acid | - |
Lasiodiplodia theobromae 2334 | 9-hydroxy-10-oxo-(12Z,15Z)-octadecadienoic acid | - |
? | |
| 4.2.1.92 | (9R)-hydroperoxy-(10E,12Z,15Z)-octadecatrienoic acid | - |
Lasiodiplodia theobromae CBS 117454 | 9-hydroxy-10-oxo-(12Z,15Z)-octadecadienoic acid | - |
? | |
| 4.2.1.92 | (9R)-hydroperoxy-(10E,12Z,15Z)-octadecatrienoic acid | - |
Lasiodiplodia theobromae CBS 122127 | 9-hydroxy-10-oxo-(12Z,15Z)-octadecadienoic acid | - |
? | |
Synonyms
| EC Number | Synonyms | Comment | Organism |
|---|---|---|---|
| 1.13.11.B6 | linolenate 9R-dioxygenase | - |
Lasiodiplodia theobromae |
| 4.2.1.92 | allene oxide synthase | - |
Lasiodiplodia theobromae |
| 4.2.1.92 | AOS | - |
Lasiodiplodia theobromae |
pH Optimum
| EC Number | pH Optimum Minimum | pH Optimum Maximum | Comment | Organism |
|---|---|---|---|---|
| 1.13.11.B6 | 7.4 | - |
assay at | Lasiodiplodia theobromae |
General Information
| EC Number | General Information | Comment | Organism |
|---|---|---|---|
| 1.13.11.B6 | additional information | fatty acid composition of Lasiodiplodia theobromae determined by GC-MS analysis after hydrolysis, overview | Lasiodiplodia theobromae |
| 1.13.11.B6 | additional information | fatty acid composition ofLasiodiplodia theobromae determined by GC-MS analysis after hydrolysis, overview | Lasiodiplodia theobromae |
| 4.2.1.92 | metabolism | jasmonic acid is synthesized from linolenic acid (18:3n-3) by sequential action of 13-lipoxygenase, allene oxide synthase, and allene oxide cyclase | Lasiodiplodia theobromae |
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