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Literature summary extracted from

  • Celis, A.I.; Gauss, G.H.; Streit, B.R.; Shisler, K.; Moraski, G.C.; Rodgers, K.R.; Lukat-Rodgers, G.S.; Peters, J.W.; DuBois, J.L.
    A structure-based mechanism for oxidative decarboxylation reactions mediated by amino acids and heme propionates in coproheme decarboxylase (HemQ) (2017), J. Am. Chem. Soc., 139, 1900-1911 .
    View publication on PubMedView publication on EuropePMC

Cloned(Commentary)

EC Number Cloned (Comment) Organism
1.3.98.5 expressed in Escherichia coli Tuner (DE3) cells Geobacillus stearothermophilus

Natural Substrates/ Products (Substrates)

EC Number Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
1.3.98.5 Fe-coproporphyrin III + H2O2 Geobacillus stearothermophilus
-
harderoheme III + CO2 + H2O
-
?
1.3.98.5 Fe-coproporphyrin III + H2O2 Geobacillus stearothermophilus overall reaction protoheme + CO2 + H2O
-
?
1.3.98.5 Fe-coproporphyrin III + H2O2 Geobacillus stearothermophilus 10
-
harderoheme III + CO2 + H2O
-
?
1.3.98.5 Fe-coproporphyrin III + H2O2 Geobacillus stearothermophilus 10 overall reaction protoheme + CO2 + H2O
-
?
1.3.98.5 harderoheme III + H2O2 Geobacillus stearothermophilus
-
protoheme + CO2 + H2O
-
?
1.3.98.5 harderoheme III + H2O2 Geobacillus stearothermophilus 10
-
protoheme + CO2 + H2O
-
?

Organism

EC Number Organism UniProt Comment Textmining
1.3.98.5 Geobacillus stearothermophilus A0A0K2H9D8
-
-
1.3.98.5 Geobacillus stearothermophilus 10 A0A0K2H9D8
-
-

Purification (Commentary)

EC Number Purification (Comment) Organism
1.3.98.5 anion exchange column chromatography and S-200 Sephacryl gel filtration Geobacillus stearothermophilus

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.3.98.5 Fe-coproporphyrin III + H2O2
-
Geobacillus stearothermophilus harderoheme III + CO2 + H2O
-
?
1.3.98.5 Fe-coproporphyrin III + H2O2
-
Geobacillus stearothermophilus 10 harderoheme III + CO2 + H2O
-
?
1.3.98.5 Fe-coproporphyrin III + H2O2 overall reaction Geobacillus stearothermophilus protoheme + CO2 + H2O
-
?
1.3.98.5 Fe-coproporphyrin III + H2O2 overall reaction Geobacillus stearothermophilus 10 protoheme + CO2 + H2O
-
?
1.3.98.5 harderoheme III + H2O2
-
Geobacillus stearothermophilus protoheme + CO2 + H2O
-
?
1.3.98.5 harderoheme III + H2O2
-
Geobacillus stearothermophilus 10 protoheme + CO2 + H2O
-
?
1.3.98.5 Mn(III) coproporphyrinate III + H2O2 coproporphyrinate III = tetrakis-2,4,6,7-propionate-protoporphyrin Geobacillus stearothermophilus ?
-
?
1.3.98.5 Mn(III) coproporphyrinate III + H2O2 coproporphyrinate III = tetrakis-2,4,6,7-propionate-protoporphyrin Geobacillus stearothermophilus 10 ?
-
?

Synonyms

EC Number Synonyms Comment Organism
1.3.98.5 coproheme decarboxylase
-
Geobacillus stearothermophilus
1.3.98.5 HemQ
-
Geobacillus stearothermophilus