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Results 1 - 4 of 4
EC Number
2-oxoglutarate + O2 = ethene + 3 CO2 + H2O
2-oxoglutarate + O2 = ethene + 3 CO2 + H2O
mechanism of ethylene formation, and two-pathway reaction mechanism of EFE, structure-function relationship
2-oxoglutarate + O2 = ethene + 3 CO2 + H2O
Pseudomonas syringae ethylene-forming enzyme reveal a branched mechanism. In one branch, an apparently typical 2-oxoglutarate oxygenase reaction to give succinate, carbon dioxide, and sometimes pyrroline-5-carboxylate occurs, reaction of EC Alternatively, Grob-type oxidative fragmentation of a 2-oxoglutarate-derived intermediate occurs to give ethylene and carbon dioxide, EC Fragmentation to give ethylene is promoted by binding of L-arginine in a nonoxidized conformation and of 2-oxoglutarate in an unprecedented high-energy conformation that favors ethylene, relative to succinate formation. Induced fit reaction mechanism, detailed overview
2-oxoglutarate + O2 = ethene + 3 CO2 + H2O
reaction mechanism, overview
Results 1 - 4 of 4