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Results 1 - 4 of 4
EC Number Reaction Commentary Reference
Display the word mapDisplay the reaction diagram Show all sequences 1.13.12.192-oxoglutarate + O2 = ethene + 3 CO2 + H2O - -
Display the word mapDisplay the reaction diagram Show all sequences 1.13.12.192-oxoglutarate + O2 = ethene + 3 CO2 + H2O mechanism of ethylene formation, and two-pathway reaction mechanism of EFE, structure-function relationship -, 742750
Display the word mapDisplay the reaction diagram Show all sequences 1.13.12.192-oxoglutarate + O2 = ethene + 3 CO2 + H2O Pseudomonas syringae ethylene-forming enzyme reveal a branched mechanism. In one branch, an apparently typical 2-oxoglutarate oxygenase reaction to give succinate, carbon dioxide, and sometimes pyrroline-5-carboxylate occurs, reaction of EC 1.13.11.34. Alternatively, Grob-type oxidative fragmentation of a 2-oxoglutarate-derived intermediate occurs to give ethylene and carbon dioxide, EC 1.13.12.19. Fragmentation to give ethylene is promoted by binding of L-arginine in a nonoxidized conformation and of 2-oxoglutarate in an unprecedented high-energy conformation that favors ethylene, relative to succinate formation. Induced fit reaction mechanism, detailed overview 743692
Display the word mapDisplay the reaction diagram Show all sequences 1.13.12.192-oxoglutarate + O2 = ethene + 3 CO2 + H2O reaction mechanism, overview -, 742153
Results 1 - 4 of 4