EC Number |
Reaction |
Reference |
---|
1.13.11.46 | 4-hydroxyphenylpyruvate + O2 = (S)-4-hydroxymandelate + CO2 |
HMS uses Fe(IV)=O to perform hydroxylation of the benzylic carbon, reaction mechanism with electrophilic attack on the aromatic ring, and HMS catalytic cycle, overview |
724365 |
1.13.11.46 | 4-hydroxyphenylpyruvate + O2 = (S)-4-hydroxymandelate + CO2 |
one oxygen from molecular oxygen is incorporated into the carboxyl group and one into the benzylic hydroxyl group |
285255 |
1.13.11.46 | 4-hydroxyphenylpyruvate + O2 = (S)-4-hydroxymandelate + CO2 |
reaction mechanism, overview |
724325, 724392 |