Any feedback?
Please rate this page
(search_result.php)
(0/150)

BRENDA support

Refine search

Search Reaction

show results
Don't show organism specific information (fast!)
Search organism in taxonomic tree (slow, choose "exact" as search mode, e.g. "mammalia" for rat,human,monkey,...)
(Not possible to combine with the first option)
Refine your search

Search term:

Results 1 - 6 of 6
EC Number Reaction Commentary Reference
Show all pathways known for 5.5.1.1Display the word mapDisplay the reaction diagram Show all sequences 5.5.1.1(+)-muconolactone = cis,cis-muconate a concerted or stepwise mechanism involving carbonium ion or covalent intermediates are not likely to be operative for the enzyme-catalyzed syn (cis) elimination 3651
Show all pathways known for 5.5.1.1Display the word mapDisplay the reaction diagram Show all sequences 5.5.1.1(+)-muconolactone = cis,cis-muconate in the reverse reaction the alpha proton of muconolactone is abstracted by a homolog of Lys166(Lys169) to generate an enolic intermediate, this intermediate undergoes vinylopous beta-elimination of the remote carboxylate group to produce cis,cis-muconate 3644
Show all pathways known for 5.5.1.1Display the word mapDisplay the reaction diagram Show all sequences 5.5.1.1(+)-muconolactone = cis,cis-muconate Mn2+ and Lys167 provide electrophilic stabilization of the enol/enolate intermediate that is formed during the course of the reaction -, 3645
Show all pathways known for 5.5.1.1Display the word mapDisplay the reaction diagram Show all sequences 5.5.1.1(+)-muconolactone = cis,cis-muconate reaction may proceed through formation of an intermediate carbanion located alpha to a carboxyl group, subsequent protonation of this putative carbanion, the carbanion is generated by attack of the remote carboxylate group on a double bond 3649
Show all pathways known for 5.5.1.1Display the word mapDisplay the reaction diagram Show all sequences 5.5.1.1(+)-muconolactone = cis,cis-muconate reaction mechanism, DFT QM/MM calculations and structure-function relationship, overview 715976
Show all pathways known for 5.5.1.1Display the word mapDisplay the reaction diagram Show all sequences 5.5.1.1(+)-muconolactone = cis,cis-muconate syn lactonization 3646
Results 1 - 6 of 6