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Results 1 - 6 of 6
EC Number
Substrates
Commentary Substrates
Organism
Products
Commentary (Products)
Reversibility
prosolanapyrone II + O2
-
prosolanapyrone III + H2O2
-
?
prosolanapyrone II + O2
-
prosolanapyrone III + H2O2
-
?
prosolanapyrone II + O2
the enzyme is involved in solanapyrone biosynthesis
prosolanapyrone III + H2O2
-
?
prosolanapyrone II + O2
the bifunctional enzyme catalyses the oxidation of prosolanapyrone II and the subsequent cycloaddition of the product prosolanapyrone III to (-)-solanapyrone A
prosolanapyrone III + H2O2
in an enzyme-catalyzed Diels–Alder reaction the product prosolanapyrone III is isomerized to solanapyrone A (exo Diels-Alder cyclization, [4+2] cycloaddition). Solanapyrone D (endo Diels-Alder cyclization) is formed by a nonenzymatic Diels-Alder cyclization of prosolanopyrone III in polar solvents. The enzyme coverts prosolanapyrone II into solanapyrone A, solanapyrone D and prosolanapyrone III in the ratio 7:1:1
?
prosolanapyrone II + O2
the enzyme is involved in solanapyrone biosynthesis
prosolanapyrone III + H2O2
-
?
prosolanapyrone II + O2
the bifunctional enzyme catalyses the oxidation of prosolanapyrone II and the subsequent cycloaddition of the product prosolanapyrone III to (-)-solanapyrone A
prosolanapyrone III + H2O2
in an enzyme-catalyzed Diels–Alder reaction the product prosolanapyrone III is isomerized to solanapyrone A (exo Diels-Alder cyclization, [4+2] cycloaddition). Solanapyrone D (endo Diels-Alder cyclization) is formed by a nonenzymatic Diels-Alder cyclization of prosolanopyrone III in polar solvents. The enzyme coverts prosolanapyrone II into solanapyrone A, solanapyrone D and prosolanapyrone III in the ratio 7:1:1
?
Results 1 - 6 of 6