(9E,11Z,15E)-octadeca-9,11,15-trienoic acid + O2
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(9E,11Z,15E)-octadeca-9,11,15-trienoic acid + O2
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?
-
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(9Z,12Z)-octadeca-9,12-dienoic acid + O2
i.e. linoleic acid
(12Z)-9-hydroxy-10-oxo-12-octadecenoic acid
the alpha-ketol is the main metabolite formed from (9R)-hydroperoxyoctadecadienoic acid
?
(9Z,12Z)-octadeca-9,12-dienoic acid + O2
i.e. linoleic acid
(12Z)-9-hydroxy-10-oxo-12-octadecenoic acid
the alpha-ketol is the main metabolite formed from (9R)-hydroperoxyoctadecadienoic acid
?
(9Z,12Z)-octadeca-9,12-dienoic acid + O2
i.e. linoleic acid
(12Z)-9-hydroxy-10-oxo-12-octadecenoic acid
the alpha-ketol is the main metabolite formed from (9R)-hydroperoxyoctadecadienoic acid
?
(9Z,12Z)-octadeca-9,12-dienoic acid + O2
i.e. linoleic acid
(12Z)-9-hydroxy-10-oxo-12-octadecenoic acid
the alpha-ketol is the main metabolite formed from (9R)-hydroperoxyoctadecadienoic acid
?
(9Z,12Z)-octadeca-9,12-dienoic acid + O2
alpha-linoleate is converted via two intermediates, (9Z,11S,12Z)-11-hydroperoxy-9,12-octadecenoate and (9Z,11E,13R)-13-hydroperoxy-9,12-octadecadienoate, which are isomerized to the end product, probably after oxidation to peroxyl radicals, beta-fragmentation, and oxygen insertion at C-9
(9S,10E,12Z)-9-hydroperoxy-octadeca-10,12-dienoate
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?
(9Z,12Z)-octadeca-9,12-dienoic acid + O2
alpha-linoleate is converted via two intermediates, (9Z,11S,12Z)-11-hydroperoxy-9,12-octadecenoate and (9Z,11E,13R)-13-hydroperoxy-9,12-octadecadienoate, which are isomerized to the end product, probably after oxidation to peroxyl radicals, beta-fragmentation, and oxygen insertion at C-9
(9S,10E,12Z)-9-hydroperoxy-octadeca-10,12-dienoate
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?
(9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + O2
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?
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?
(9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + O2
gamma-linoleate is oxidized at C-9, C-11, and C-13
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