EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
1.13.11.B6 | (9E,11Z,15E)-octadeca-9,11,15-trienoic acid + O2 |
- |
Nakataea oryzae |
? |
- |
? |
1.13.11.B6 | (9E,11Z,15E)-octadeca-9,11,15-trienoic acid + O2 |
- |
Nakataea oryzae CBS 288.54 |
? |
- |
? |
1.13.11.B6 | (9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + O2 |
- |
Zea mays |
? |
- |
? |
1.13.11.B6 | linoleate + O2 |
- |
Zea mays |
(9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate |
- |
? |
1.13.11.B6 | linoleate + O2 |
- |
Oryza sativa |
(9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate + (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate |
the ratio of (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate to (9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate is 4:3 |
? |
1.13.11.B6 | linoleate + O2 |
- |
Corylus avellana |
(9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate + (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate |
(9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate is the main product (about 70% of the total hydroperoxides), predominantly S configuration |
? |
1.13.11.B6 | linoleate + O2 |
- |
Oryza sativa |
(9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate + (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate |
dual positional specificity. The ratio of (10E,12Z)-9-hydroperoxy-10,12-octadecadienoate to (9Z,11E)-13-hydroperoxy-9,11-octadecadienoate is 4:3. Both products are predominantly in the S configuration |
? |
1.13.11.B6 | linoleate + O2 |
- |
Solanum tuberosum |
(10E,12Z)-9-hydroperoxy-10,12-octadecadienoate + (9Z,11E)-13-hydroperoxy-9,11-octadecadienoate |
dual positional specificity: the enzyme produces roughly equimolar amounts of (10E,12Z)-9-hydroperoxy-10,12-octadecadienoate and (9Z,11E)-13-hydroperoxy-9,11-octadecadienoate. The R/S stereoconfiguration of the products is not determined |
? |
1.13.11.B6 | linoleate + O2 |
- |
Arachis hypogaea |
(10E,12Z)-9-hydroperoxy-10,12-octadecadienoate + (9Z,11E)-13-hydroperoxy-9,11-octadecadienoate |
the linoleic acid oxidation products are ca. 70% and (9Z,11E)-13-hydroperoxy-9,11-octadecadienoate and 30% (10E,12Z)-9-hydroperoxy-10,12-octadecadienoate both of which are mainly the S-stereoisomer |
? |
1.13.11.B6 | linoleate + O2 |
- |
Pisum sativum |
(10E,12Z)-9-hydroperoxy-10,12-octadecadienoate + (9Z,11E)-13-hydroperoxy-9,11-octadecadienoate |
the ratio of (9Z,11E)-13-hydroperoxy-11,13-octadecadienoate to (10E,12Z)-9-hydroperoxy-10,12-octadecadienoate is 1:2 for pea seed LOX-3 and recombinant LOX-3. The R/S stereoconfiguration of the products is not determined |
? |