EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
1.13.11.B6 | (9E,11Z,15E)-octadeca-9,11,15-trienoic acid + O2 |
- |
Nakataea oryzae |
? |
- |
? |
1.13.11.B6 | (9E,11Z,15E)-octadeca-9,11,15-trienoic acid + O2 |
- |
Nakataea oryzae CBS 288.54 |
? |
- |
? |
1.13.11.B6 | (9Z,12Z)-octadeca-9,12-dienoic acid + O2 |
i.e. linoleic acid |
Lasiodiplodia theobromae |
(12Z)-9-hydroxy-10-oxo-12-octadecenoic acid |
the alpha-ketol is the main metabolite formed from (9R)-hydroperoxyoctadecadienoic acid |
? |
1.13.11.B6 | (9Z,12Z)-octadeca-9,12-dienoic acid + O2 |
i.e. linoleic acid |
Lasiodiplodia theobromae 2334 |
(12Z)-9-hydroxy-10-oxo-12-octadecenoic acid |
the alpha-ketol is the main metabolite formed from (9R)-hydroperoxyoctadecadienoic acid |
? |
1.13.11.B6 | (9Z,12Z)-octadeca-9,12-dienoic acid + O2 |
i.e. linoleic acid |
Lasiodiplodia theobromae CBS 117454 |
(12Z)-9-hydroxy-10-oxo-12-octadecenoic acid |
the alpha-ketol is the main metabolite formed from (9R)-hydroperoxyoctadecadienoic acid |
? |
1.13.11.B6 | (9Z,12Z)-octadeca-9,12-dienoic acid + O2 |
i.e. linoleic acid |
Lasiodiplodia theobromae CBS 122127 |
(12Z)-9-hydroxy-10-oxo-12-octadecenoic acid |
the alpha-ketol is the main metabolite formed from (9R)-hydroperoxyoctadecadienoic acid |
? |
1.13.11.B6 | (9Z,12Z)-octadeca-9,12-dienoic acid + O2 |
alpha-linoleate is converted via two intermediates, (9Z,11S,12Z)-11-hydroperoxy-9,12-octadecenoate and (9Z,11E,13R)-13-hydroperoxy-9,12-octadecadienoate, which are isomerized to the end product, probably after oxidation to peroxyl radicals, beta-fragmentation, and oxygen insertion at C-9 |
Nakataea oryzae |
(9S,10E,12Z)-9-hydroperoxy-octadeca-10,12-dienoate |
- |
? |
1.13.11.B6 | (9Z,12Z)-octadeca-9,12-dienoic acid + O2 |
alpha-linoleate is converted via two intermediates, (9Z,11S,12Z)-11-hydroperoxy-9,12-octadecenoate and (9Z,11E,13R)-13-hydroperoxy-9,12-octadecadienoate, which are isomerized to the end product, probably after oxidation to peroxyl radicals, beta-fragmentation, and oxygen insertion at C-9 |
Nakataea oryzae CBS 288.54 |
(9S,10E,12Z)-9-hydroperoxy-octadeca-10,12-dienoate |
- |
? |
1.13.11.B6 | (9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + O2 |
- |
Zea mays |
? |
- |
? |
1.13.11.B6 | (9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + O2 |
gamma-linoleate is oxidized at C-9, C-11, and C-13 |
Nakataea oryzae |
? |
- |
? |