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Literature summary for 1.1.3.20 extracted from

  • Moreau, R.A.; Huang, A.H.C.
    Oxidation of fatty alcohol in the cotyledons of jojoba seedlings (1979), Arch. Biochem. Biophys., 194, 422-430.
    View publication on PubMed

Inhibitors

Inhibitors Comment Organism Structure
additional information no inhibitor: cyanide Simmondsia chinensis
p-chloromercuribenzoate 70% loss of activity at 0.1 mM, completely reversible with dithiothreitol Simmondsia chinensis

Localization

Localization Comment Organism GeneOntology No. Textmining
glyoxysome
-
Simmondsia chinensis 9514
-
membrane
-
Simmondsia chinensis 16020
-
oil body
-
Simmondsia chinensis
-
-

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
long-chain alcohol + O2 Simmondsia chinensis reaction in wax ester catabolism in the storage wax bodies of jojoba plant during germination ?
-
?
long-chain alcohol + O2 Simmondsia chinensis monounsaturated long-chain alcohols ?
-
?

Organism

Organism UniProt Comment Textmining
Simmondsia chinensis
-
jojoba
-

Reaction

Reaction Comment Organism Reaction ID
a long-chain alcohol + O2 = a long-chain aldehyde + H2O2 2 long-chain alcohol + O2 = 2 long-chain aldehyde + 2 H2O2 Simmondsia chinensis

Storage Stability

Storage Stability Organism
freezing overnight leads to 50% loss of activity Simmondsia chinensis

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1-docosanol + O2 i.e. behenyl alcohol, poor substrate Simmondsia chinensis docosanal + H2O2
-
?
1-eicosanol + O2 i.e. arachidyl alcohol, poor substrate Simmondsia chinensis eicosanal + H2O2
-
?
1-tetradecanol + O2
-
Simmondsia chinensis tetradecanal + H2O2
-
?
cis-11-eicosenol + O2 higher oxidation rate than saturated analog Simmondsia chinensis cis-11-eicosenal + H2O2
-
?
decanol + O2
-
Simmondsia chinensis decanal + H2O2
-
?
docosenol + O2 higher oxidation rate than saturated analog Simmondsia chinensis docosenal + H2O2
-
?
dodecanol + O2 i.e. lauryl alcohol, preferred substrate Simmondsia chinensis dodecanal + H2O2
-
?
hexadecanol + O2
-
Simmondsia chinensis hexadecanal + H2O2
-
?
long-chain alcohol + O2 reaction in wax ester catabolism in the storage wax bodies of jojoba plant during germination Simmondsia chinensis ?
-
?
long-chain alcohol + O2 monounsaturated long-chain alcohols Simmondsia chinensis ?
-
?
additional information no substrates: ethanol, palmitic acid Simmondsia chinensis ?
-
?
octadecanol + O2
-
Simmondsia chinensis octadecanal + H2O2
-
?

Temperature Stability [┬░C]

Temperature Stability Minimum [┬░C] Temperature Stability Maximum [┬░C] Comment Organism
100
-
boiling for 30 min inactivates the enzyme Simmondsia chinensis

pH Optimum

pH Optimum Minimum pH Optimum Maximum Comment Organism
9
-
1-dodecanol Simmondsia chinensis

pH Range

pH Minimum pH Maximum Comment Organism
6.6 9.3 about half-maximal activity at pH 6.6 and 9.3 Simmondsia chinensis