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Literature summary for 1.14.13.22 extracted from

  • Sole, J.; Brummund, J.; Caminal, G.; Schuerman, M.; Alvaro, G.; Guillen, M.
    Trimethyl-epsilon-caprolactone synthesis with a novel immobilized glucose dehydrogenase and an immobilized thermostable cyclohexanone monooxygenase (2019), Appl. Catal. B, 585, 117187 .
No PubMed abstract available

Application

Application Comment Organism
synthesis synthesis of trimethyl-epsilon-caprolactone using cyclohexanone monooxygenase immobilized on Mana-agarose and a highly active glucose dehydrogenase for cofactor regeneration. A biocatalyst yield of 37.3 g trimethyl-epsilon-caprolactone per g of CHMO and 474.2 g trimethyl-epsilon-caprolactone per g of glucose dehydrogenase are obtained Thermocrispum municipale

Cloned(Commentary)

Cloned (Comment) Organism
expression in Escherichia coli Thermocrispum municipale

Organism

Organism UniProt Comment Textmining
Thermocrispum municipale A0A1L1QK39
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Thermocrispum municipale DSM 44069 A0A1L1QK39
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
3,3,5-trimethyl-cyclohexanone + NADPH + H+ + O2
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Thermocrispum municipale trimethyl-epsilon-caprolactone + NADP+ + H2O
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?
3,3,5-trimethyl-cyclohexanone + NADPH + H+ + O2
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Thermocrispum municipale DSM 44069 trimethyl-epsilon-caprolactone + NADP+ + H2O
-
?