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Literature summary extracted from

  • Koch, J.; Eisenreich, W.; Bacher, A.; Fuchs, G.
    Products of enzymatic reduction of benzoyl-CoA, a key reaction in anaerobic aromatic metabolism (1993), Eur. J. Biochem., 211, 649-661.
    View publication on PubMed

Natural Substrates/ Products (Substrates)

EC Number Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
1.1.1.259 3-hydroxypimeloyl-CoA + NAD+ Rhodopseudomonas palustris first non-cyclic intermediate from benzoyl-CoA degradation pathway by beta-oxidation 3-oxopimeloyl-CoA + NADH
-
 r
1.1.1.259 3-hydroxypimeloyl-CoA + NAD+ Pseudomonas sp. first non-cyclic intermediate from benzoyl-CoA degradation pathway by beta-oxidation 3-oxopimeloyl-CoA + NADH
-
 r
1.1.1.259 3-hydroxypimeloyl-CoA + NAD+ Pseudomonas sp. K172 first non-cyclic intermediate from benzoyl-CoA degradation pathway by beta-oxidation 3-oxopimeloyl-CoA + NADH
-
 r
4.2.1.100 cyclohexa-1,5-diene-1-carbonyl-CoA + H2O Aromatoleum evansii
-
 6-hydroxycyclohex-1-enecarbonyl-CoA
-
 ?

Organism

EC Number Organism UniProt Comment Textmining
1.1.1.259 Pseudomonas sp.
-
-
-
1.1.1.259 Pseudomonas sp.
-
 anaerobically grown on benzoate and nitrate
-
1.1.1.259 Pseudomonas sp. K172
-
-
-
1.1.1.259 Rhodopseudomonas palustris
-
-
-
4.2.1.100 Aromatoleum evansii
-
-
-

Reaction

EC Number Reaction Comment Organism Reaction ID
1.1.1.259 3-hydroxypimeloyl-CoA + NAD+ = 3-oxopimeloyl-CoA + NADH + H+ Involved in the anaerobic pathway of benzoate degradation in bacteria Rhodopseudomonas palustris
a
1.1.1.259 3-hydroxypimeloyl-CoA + NAD+ = 3-oxopimeloyl-CoA + NADH + H+ Involved in the anaerobic pathway of benzoate degradation in bacteria Pseudomonas sp.
a

Source Tissue

EC Number Source Tissue Comment Organism Textmining
1.1.1.259 cell culture
-
 Rhodopseudomonas palustris
-
1.1.1.259 cell culture
-
 Pseudomonas sp.
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.1.1.259 3-hydroxypimeloyl-CoA + NAD+ first non-cyclic intermediate from benzoyl-CoA degradation pathway by beta-oxidation Rhodopseudomonas palustris 3-oxopimeloyl-CoA + NADH
-
 r
1.1.1.259 3-hydroxypimeloyl-CoA + NAD+ first non-cyclic intermediate from benzoyl-CoA degradation pathway by beta-oxidation Pseudomonas sp. 3-oxopimeloyl-CoA + NADH
-
 r
1.1.1.259 3-hydroxypimeloyl-CoA + NAD+ first non-cyclic intermediate from benzoyl-CoA degradation pathway by beta-oxidation Pseudomonas sp. K172 3-oxopimeloyl-CoA + NADH
-
 r
4.2.1.100 cyclohexa-1,5-diene-1-carbonyl-CoA + H2O
-
 Aromatoleum evansii 6-hydroxycyclohex-1-ene-1-carbonyl-CoA
-
 ?
4.2.1.100 cyclohexa-1,5-diene-1-carbonyl-CoA + H2O
-
 Aromatoleum evansii 6-hydroxycyclohex-1-enecarbonyl-CoA
-
 ?

Cofactor

EC Number Cofactor Comment Organism Structure
1.1.1.259 CoA CoA thioester formation is the first step in benzoate degradation Rhodopseudomonas palustris
1.1.1.259 CoA CoA thioester formation is the first step in benzoate degradation Pseudomonas sp.
1.1.1.259 NAD+
-
 Rhodopseudomonas palustris
1.1.1.259 NAD+
-
 Pseudomonas sp.