EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
1.14.13.B28 | more |
the enzyme also catalyzes hydrogen peroxide-driven ethylbenzene hydroxylation. The ethylbenzene hydroxylation activity is higher than the styrene epoxidation activity, maybe due to a difference in the binding affinity of the two substrates. The rate-limiting steps of ethylbenzene hydroxylation and styrene epoxidation are the same, and may be any step before formation of the active oxidant |
Sulfurisphaera tokodaii |
? |
- |
? |
1.14.13.B28 | more |
electron-transfer reaction between the electrode and heme iron. Direct electrochemistry of P450st in a didodecyldimethylammonium bromide film on a plastic formed carbon electrode is demonstrated. A quasi-reversible redox response is observed at temperatures of up to 80°C |
Sulfurisphaera tokodaii |
? |
- |
? |
1.14.13.B28 | more |
the initial activities of CYP119 in the presence of tert-butyl hydroperoxide and cumene hydroperoxide are two- and fivefold higher than that observed with H2O2. tert-Butyl hydroperoxide increases both turnover rate and the stability of the enzyme under the oxidizing reaction conditions |
Sulfolobus acidocaldarius |
? |
- |
- |
1.14.13.B28 | more |
the initial activities of CYP119 in the presence of tert-butyl hydroperoxide and cumene hydroperoxide are two- and fivefold higher than that observed with H2O2. tert-Butyl hydroperoxide increases both turnover rate and the stability of the enzyme under the oxidizing reaction conditions |
Sulfolobus acidocaldarius DSM 639 |
? |
- |
- |
1.14.13.B28 | more |
the enzyme also catalyzes hydrogen peroxide-driven ethylbenzene hydroxylation. The ethylbenzene hydroxylation activity is higher than the styrene epoxidation activity, maybe due to a difference in the binding affinity of the two substrates. The rate-limiting steps of ethylbenzene hydroxylation and styrene epoxidation are the same, and may be any step before formation of the active oxidant |
Sulfurisphaera tokodaii 7 |
? |
- |
? |
1.14.13.B28 | more |
electron-transfer reaction between the electrode and heme iron. Direct electrochemistry of P450st in a didodecyldimethylammonium bromide film on a plastic formed carbon electrode is demonstrated. A quasi-reversible redox response is observed at temperatures of up to 80°C |
Sulfurisphaera tokodaii 7 |
? |
- |
? |
1.14.13.B28 | styrene + cumen hydroperoxide |
- |
Sulfolobus acidocaldarius |
styrene epoxide + ? |
- |
? |
1.14.13.B28 | styrene + cumen hydroperoxide |
- |
Sulfolobus acidocaldarius DSM 639 |
styrene epoxide + ? |
- |
? |
1.14.13.B28 | styrene + tert-butyl hydroperoxide |
- |
Sulfolobus acidocaldarius |
styrene epoxide + ? |
- |
? |
1.14.13.B28 | styrene + tert-butyl hydroperoxide |
- |
Sulfolobus acidocaldarius DSM 639 |
styrene epoxide + ? |
- |
? |