EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
1.14.14.84 | linalool + 2 [reduced NADPH-hemoprotein reductase] + 2 O2 |
- |
Novosphingobium aromaticivorans |
(6E)-8-oxolinalool + 2 [oxidized NADPH-hemoprotein reductase] + 3 H2O |
- |
? |
1.14.14.84 | linalool + 2 [reduced NADPH-hemoprotein reductase] + 2 O2 |
- |
Novosphingobium aromaticivorans |
(6E)-8-oxolinalool + 2 [oxidized NADPH-hemoprotein reductase] + 3 H2O |
NMR spectroscopy product analysis |
? |
1.14.14.84 | linalool + 2 [reduced NADPH-hemoprotein reductase] + 2 O2 |
- |
Novosphingobium aromaticivorans ATCC 700278D-5 |
(6E)-8-oxolinalool + 2 [oxidized NADPH-hemoprotein reductase] + 3 H2O |
- |
? |
1.14.14.84 | (6E)-8-hydroxylinalool + [reduced NADPH-hemoprotein reductase] + O2 |
- |
Pseudomonas putida |
(6E)-8-oxolinalool + [oxidized NADPH-hemoprotein reductase] + H2O |
product analysis by mass spectrometry |
? |
1.14.14.84 | (E)-3,7-dimethylocta-1,6-dien-3,8-diol + [reduced NADPH-hemoprotein reductase] + O2 |
8-hydroxylinalool |
Pseudomonas putida |
8-oxolinalool + [oxidized NADPH-hemoprotein reductase] + H2O |
- |
? |
1.14.14.84 | 3,7-dimethylocta-1,6-dien-3-ol + [reduced NADPH-hemoprotein reductase] + O2 |
- |
Pseudomonas putida |
(E)-3,7-dimethylocta-1,6-dien-3,8-diol + [oxidized NADPH-hemoprotein reductase] + H2O |
8-hydroxylinalool |
? |
1.14.14.84 | 3,7-dimethylocta-1,6-dien-3-ol + [reduced NADPH-hemoprotein reductase] + O2 |
both isomers of linalool, strict substrate specificity: geraniol, nerol or citronellol are not hydroxylated |
Pseudomonas putida |
(E)-3,7-dimethylocta-1,6-dien-3,8-diol + [oxidized NADPH-hemoprotein reductase] + H2O |
- |
? |
1.14.14.84 | 3,7-dimethylocta-1,6-dien-3-ol + [reduced NADPH-hemoprotein reductase] + O2 |
linalool, initial reaction in linalool catabolism |
Pseudomonas putida |
(E)-3,7-dimethylocta-1,6-dien-3,8-diol + [oxidized NADPH-hemoprotein reductase] + H2O |
- |
? |
1.14.14.84 | 6-methyl-hex-5-en-2-ol + [reduced NADPH-hemoprotein reductase] + O2 |
- |
Pseudomonas putida |
6-methyl-hex-5-en-2-one + [oxidized NADPH-hemoprotein reductase] + H2O |
- |
ir |
1.14.14.84 | linalool + 2 [reduced NADPH-hemoprotein reductase] + 2 O2 |
- |
Pseudomonas putida |
(6E)-8-oxolinalool + 2 [oxidized NADPH-hemoprotein reductase] + 3 H2O |
- |
? |