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EC Number Substrates Commentary Substrates Organism Products Commentary (Products) Reversibility
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.182-chloro-5,5-dimethyl-1,3-cyclohexane-dione HBr + H2O2 2-chloro-5,5-dimethyl-1,3-cyclohexane-dione (mcd) is the standard substrate for the determination of haloperoxidase activity using H2O2 as the oxidant Ascophyllum nodosum ? + 2 H2O - ?
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.18Br- + H2O2 + (3R)-3-bromo-2,6-dimethylhept-5-en-2-ol - Ascophyllum nodosum 3,5-dibromo-2,6-dimethylheptane-2,6-diol + H2O 70% yield, at pH 6.0 ?
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.18Br- + H2O2 + 1-phenylpent-4-en-1-ol - Ascophyllum nodosum 4-bromo-1-phenylpentane-1,5-diol + 5-bromo-1-phenylpentane-1,4-diol + 2-(bromomethyl)-5-phenyltetrahydrofuran + H2O 30% yield of 4-bromo-1-phenylpentane-1,5-diol, 28% yield of 5-bromo-1-phenylpentane-1,4-diol, and 25% yield of 2-(bromomethyl)-5-phenyltetrahydrofuran, at pH 6.0 ?
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.18Br- + H2O2 + 2-methoxyphenol - Ascophyllum nodosum 2-bromo-6-methoxyphenol + 4-bromo-6-methoxyphenol + H2O 56% of product, in a 21/79 mixture of o-/p-regioisomers, plus 10% 2,4-dibromo-6-methoxyphenol ?
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.18Br- + H2O2 + 2-methylphenol - Ascophyllum nodosum 2-bromo-6-methylphenol + 4-bromo-6-methylphenol + H2O 68% of product, in a 16/84 mixture of o-/p-regioisomers, plus 4% 2,4-dibromophenol ?
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.18Br- + H2O2 + 2-t-butylphenol - Ascophyllum nodosum 2-bromo-6-t-butylphenol + 4-bromo-6-t-butylphenol + H2O 42% of product, in a 36/64 mixture of o-/p-regioisomers, plus 2% 2,4-dibromo-6-t-butylphenol ?
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.18Br- + H2O2 + 5-methyl-1-phenylhex-4-en-1-ol - Ascophyllum nodosum 4-bromo-5-methyl-1-phenylhexane-1,5-diol + 2-(1-bromo-1-methylethyl)-5-phenyltetrahydrofuran + 3-bromo-2,2-dimethyl-6-phenyltetrahydro-2H-pyran + H2O 69% yield of 4-bromo-5-methyl-1-phenylhexane-1,5-diol, 6% yield of 2-(1-bromo-1-methylethyl)-5-phenyltetrahydrofuran, and 9% yield of 3-bromo-2,2-dimethyl-6-phenyltetrahydro-2H-pyran, at pH 6.0 ?
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.18Br- + H2O2 + methyl pyrrole-2-carboxylate - Ascophyllum nodosum methyl 5-amino-4-bromocyclopenta-1,3-diene-1-carboxylate + methyl 5-amino-3-bromocyclopenta-1,3-diene-1-carboxylate + methyl 5-amino-3,4-dibromocyclopenta-1,3-diene-1-carboxylate + H2O 5% yield of methyl 5-amino-4-bromocyclopenta-1,3-diene-1-carboxylate, 59% yield of methyl 5-amino-3-bromocyclopenta-1,3-diene-1-carboxylate, and 5% yield of methyl 5-amino-3,4-dibromocyclopenta-1,3-diene-1-carboxylate, at pH 6.3 and 25°C ?
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.18Br- + H2O2 + methyl pyrrole-2-carboxylate - Ascophyllum nodosum methyl 4-bromo-1H-pyrrole-2-carboxylate + methyl 5-bromo-1H-pyrrole-2-carboxylate + H2O quantitative conversion within 24 h, 94% of product in 93/7 ratio of 4-/5-substituted regioisomers ?
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.18Br- + H2O2 + monochlorodimedone - Ascophyllum nodosum H2O + ? - ?
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