2.5.1.94: adenosyl-chloride synthase

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For detailed information about adenosyl-chloride synthase, go to the full flat file.

Word Map on EC 2.5.1.94

2.5.1.94

chlorinate

halogen

fluorinase

polyketide

halogenase

tropica

salinispora

halide

cattleya

salinosporamide

fluorination

synthesis

flavin-dependent

cl

fluoride

congener

desolvation

chemoenzymatic

non-ribosomal

flavin

fad-dependent

Reaction

Synonyms

5'-chloro-5'-deoxyadenosine synthase, AclH, chlorinase, Cla1, ClA2, S-adenosyl-L-methionine-dependent chlorinase, SalL, SAM-dependent chlorinase

ECTree

2 Transferases

2.5 Transferring alkyl or aryl groups, other than methyl groups

2.5.1 Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)

2.5.1.94 adenosyl-chloride synthase

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Results	in table
260	AA Sequence
3	Application
5	Cloned(Commentary)
2	Cofactor
1	Crystallization (Commentary)
7	General Information
16	kcat/KM [mM/s]
15	KM Value [mM]
1	Molecular Weight [Da]
5	Natural Substrates/ Products (Substrates)
19	Organism
1	Pathway
6	PDB ID
9	Protein Variants
3	Purification (Commentary)
1	Reaction
2	Reaction Type
14	Reference
40	Substrates and Products (Substrate)
3	Subunits
22	Synonyms
1	Systematic Name
16	Turnover Number [1/s]

Systematic Name

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Systematic Name on EC 2.5.1.94 - adenosyl-chloride synthase

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S-adenosyl-L-methionine:chloride adenosyltransferase

This enzyme, isolated from the marine bacterium Salinispora tropica, catalyses an early step in the pathway leading to biosynthesis of the proteosome inhibitor salinosporamide A. The enzyme is very similar to EC 2.5.1.63, adenosyl-fluoride synthase, but does not accept fluoride.