1.14.13.187: L-evernosamine nitrososynthase
This is an abbreviated version!
For detailed information about L-evernosamine nitrososynthase, go to the full flat file.
Word Map on EC 1.14.13.187
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1.14.13.187
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thymidine
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monooxygenase
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micromonospora
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anthracycline
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flavin-dependent
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africana
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peucetius
- 1.14.13.187
- thymidine
- monooxygenase
- micromonospora
-
anthracycline
-
flavin-dependent
- africana
- peucetius
Reaction
Synonyms
DnmZ, nitrososynthase, ORF36
ECTree
1.14.13.187 L-evernosamine nitrososynthaseAdvanced search results
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results (Natural Substrates Products
Natural Substrates Products on EC 1.14.13.187 - L-evernosamine nitrososynthase
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NATURAL SUBSTRATE 
NATURAL PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate)
(Substrate)
LITERATURE
(Substrate)
(Substrate)
COMMENTARY
(Product)
(Product)
LITERATURE
(Product)
(Product)
REVERSIBILITY
r=reversible
ir=irreversible
?=not specified
r=reversible
ir=irreversible
?=not specified
dTDP-beta-L-evernosamine + 2 NADPH + 2 H+ + 2 O2
dTDP-2,3,6-trideoxy-3-C-methyl-4-O-methyl-3-nitroso-beta-L-arabino-hexopyranose + 2 NADP+ + 3 H2O
dTDP-beta-L-evernosamine + 2 NADPH + 2 H+ + 2 O2
dTDP-2,3,6-trideoxy-3-C-methyl-4-O-methyl-3-nitroso-beta-L-arabino-hexopyranose + 2 NADP+ + 3 H2O
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overall reaction, dTDP-beta-L-evernosamine i.e. dTDP-3-amino-2,3,6-trideoxy-3-C-methyl-4-O-methyl-beta-L-arabino-hexopyranose. The nitroso group is probably spontaneously oxidized to a nitro group giving dTDP-beta-L-evernitrose, which is involved in the biosynthesis of the antibiotic everninomycin
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-
?
dTDP-beta-L-evernosamine + 2 NADPH + 2 H+ + 2 O2
dTDP-2,3,6-trideoxy-3-C-methyl-4-O-methyl-3-nitroso-beta-L-arabino-hexopyranose + 2 NADP+ + 3 H2O
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overall reaction, dTDP-beta-L-evernosamine i.e. dTDP-3-amino-2,3,6-trideoxy-3-C-methyl-4-O-methyl-beta-L-arabino-hexopyranose. The nitroso group is probably spontaneously oxidized to a nitro group giving dTDP-beta-L-evernitrose, which is involved in the biosynthesis of the antibiotic everninomycin
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-
?
dTDP-beta-L-evernosamine + 2 NADPH + 2 H+ + 2 O2
dTDP-2,3,6-trideoxy-3-C-methyl-4-O-methyl-3-nitroso-beta-L-arabino-hexopyranose + 2 NADP+ + 3 H2O
overall reaction
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-
?
