1.14.13.166: 4-nitrocatechol 4-monooxygenase
This is an abbreviated version!
For detailed information about 4-nitrocatechol 4-monooxygenase, go to the full flat file.
Word Map on EC 1.14.13.166
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1.14.13.166
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hydroquinone
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fad
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1,2-dioxygenase
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burkholderia
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monooxygenation
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putida
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catechols
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hydroxyquinol
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two-component
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single-component
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p-benzoquinone
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1,4-benzoquinone
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para-benzoquinone
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arthrobacter
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2-chloro-4-nitrophenol
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flavin
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pesticides
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dioxygenase
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priority
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maleylacetate
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ortho
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trihydroxybenzene
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chlorophenol
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glide
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dinucleotide-dependent
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flavin-dependent
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prosa
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bioremediation
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insecticide
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maestro
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sphaericus
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3-methyl-4-nitrophenol
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cepacia
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fenitrothion
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semialdehyde
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procheck
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errat
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parathion
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methylhydroquinone
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desmond
- 1.14.13.166
- hydroquinone
- fad
-
1,2-dioxygenase
- burkholderia
-
monooxygenation
- putida
- catechols
- hydroxyquinol
-
two-component
-
single-component
- p-benzoquinone
- 1,4-benzoquinone
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para-benzoquinone
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arthrobacter
- 2-chloro-4-nitrophenol
- flavin
- pesticides
- dioxygenase
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priority
- maleylacetate
-
ortho
-
trihydroxybenzene
- chlorophenol
-
glide
-
dinucleotide-dependent
-
flavin-dependent
-
prosa
-
bioremediation
-
insecticide
-
maestro
- sphaericus
- 3-methyl-4-nitrophenol
-
cepacia
- fenitrothion
- semialdehyde
-
procheck
-
errat
- parathion
- methylhydroquinone
-
desmond
Reaction
Synonyms
4-nitrophenol 4-monooxygenase/4-nitrocatechol 2-monooxygenase, NpcA, npcB, NpdA2, p-nitrophenol monooxygenase, p-nitrophenol monooxygenase-II, para-nitrophenol 4-monooxygenase, PdcA, pentachlorophenol-4-monooxygenase, PNP 4-monooxygenase, PNP monooxygenase, pnpA, two-component PNP monooxygenase
ECTree
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Substrates Products
Substrates Products on EC 1.14.13.166 - 4-nitrocatechol 4-monooxygenase
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REACTION DIAGRAM
2,4,5-trichlorophenol + NADH + H+ + O2
2,5-dichlorohydroquinone + 5-chloro-2-hydroxyquinol + ? + NAD+ + H2O
poor substrate
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-
?
2,4,6-trichlorophenol + NADH + H+ + O2
2,6-dichlorohydroquinone + 6-chloro-2-hydroxyquinol + ? + NAD+ + H2O
poor substrate
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-
?
2,4-dinitrophenol + NADH + H+ + O2
2-nitrohydroquinone + nitrite + NAD+ + H2O
poor substrate
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-
?
3-nitrophenol + NADH + H+ + O2
3-nitrohydroquinone + NAD+ + H2O
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-
-
?
4-chlorocatechol + NADH + H+ + O2
5-chlorohydroxyquinol + ? + NAD+ + H2O
good substrate
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-
?
4-chlorophenol + NADH + H+ + O2
1,2,4-trihydroxybenzene + 2-hydroxy-1,4-benzoquinone + ? + NAD+ + H2O
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-
-
?
4-chlororesorcinol + NADH + H+ + O2
1,2,4-trihydroxybenzene + ? + NAD+ + H2O
good substrate
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-
?
4-cresol + NADH + H+ + O2
4-hydroxy-4-methyl-2,5-cyclohexadien-1-one + NAD+ + H2O
poor substrate
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-
?
4-methylcatechol + NADH + H+ + O2
? + NAD+ + H2O
poor substrate
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-
?
4-nitrocatechol + NADPH + H+ + O2
1,2,4-trihydroxybenzene + nitrite + NADP+ + H2O
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monooxygenation, the enzyme completely degrades 0.1 mM 4-nitrocatechol in 80 min
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-
?
4-nitrophenol + NADH + H+ + O2
2-hydroxy-1,4-benzoquinone + 1,2,4-trihydroxybenzene + nitrite + NAD+ + H2O
best substrate
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-
?
phenol + NADH + H+ + O2
hydroquinone + ? + NAD+ + H2O
poor substrate
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-
?
1,2,4-trihydroxybenzene + nitrite + NAD(P)+ + H2O
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about 31.2% of the nitro substituent of 4-nitrocatechol (initial concentration of 0.2 mM) is cleaved to yield nitrite over 2 h
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-
?
4-nitrocatechol + NAD(P)H + H+ + O2
1,2,4-trihydroxybenzene + nitrite + NAD(P)+ + H2O
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about 31.2% of the nitro substituent of 4-nitrocatechol (initial concentration of 0.2 mM) is cleaved to yield nitrite over 2 h
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-
?
2-hydroxy-1,4-benzoquinone + nitrite + NAD(P)+ + H2O
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-
-
?
4-nitrocatechol + NAD(P)H + H+ + O2
2-hydroxy-1,4-benzoquinone + nitrite + NAD(P)+ + H2O
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-
-
?
4-nitrocatechol + NAD(P)H + H+ + O2
2-hydroxy-1,4-benzoquinone + nitrite + NAD(P)+ + H2O
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-
-
?
4-nitrocatechol + NAD(P)H + H+ + O2
2-hydroxy-1,4-benzoquinone + nitrite + NAD(P)+ + H2O
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-
-
?
4-nitrocatechol + NAD(P)H + H+ + O2
2-hydroxy-1,4-benzoquinone + nitrite + NAD(P)+ + H2O
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-
-
?
1,2,4-trihydroxybenzene + nitrite + NAD+ + H2O
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-
-
?
4-nitrocatechol + NADH + H+ + O2
1,2,4-trihydroxybenzene + nitrite + NAD+ + H2O
-
-
-
?
2-hydroxy-1,4-benzoquinone + nitrite + NAD+ + H2O
good substrate
-
-
?
4-nitrocatechol + NADH + H+ + O2
2-hydroxy-1,4-benzoquinone + nitrite + NAD+ + H2O
-
-
-
?
4-nitrocatechol + NADH + H+ + O2
2-hydroxy-1,4-benzoquinone + nitrite + NAD+ + H2O
-
-
-
-
?
4-nitrocatechol + NADH + H+ + O2
2-hydroxy-1,4-benzoquinone + nitrite + NAD+ + H2O
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-
-
?
4-nitrocatechol + NADH + H+ + O2
2-hydroxy-1,4-benzoquinone + nitrite + NAD+ + H2O
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-
-
?
?
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hydroquinone, resorcinol, and catechol are not substrates for NpdA2
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-
?
additional information
?
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hydroquinone, resorcinol, and catechol are not substrates for NpdA2
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-
?
additional information
?
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NADPH does not support 4-nitrophenol or 4-nitrocatechol oxidation
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-
?
additional information
?
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NADPH does not support 4-nitrophenol or 4-nitrocatechol oxidation
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-
?