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Information on EC 1.1.1.71 - alcohol dehydrogenase [NAD(P)+]
for references in articles please use BRENDA:EC1.1.1.71
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EC Tree 1 Oxidoreductases
1.1 Acting on the CH-OH group of donors
1.1.1 With NAD+ or NADP+ as acceptor
1.1.1.71 alcohol dehydrogenase [NAD(P)+]
IUBMB Comments
Reduces aliphatic aldehydes of carbon chain length from 2 to 14, with greatest activity on C4, C6 and C8 aldehydes; also reduces retinal to retinol.
The expected taxonomic range for this enzyme is: Bacteria, Eukaryota, Archaea
- 1.1.1.71
-
retinoids
- thermoanaerobacter
- all-trans-retinaldehyde
-
retinyl
-
ethanolicus
- all-trans-retinol
-
r-1-phenylethanol
-
cyp26a1
- akr1b10
showSynonyms
dhrs3, retinaldehyde reductase, tesadh, retsdr1, nadph-dependent alcohol dehydrogenase, adh12, nad(p)h-dependent aldehyde reductase, tsib_0319, phadh, nad(p)h-dependent adh, more
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SYNONYM 
ORGANISM
UNIPROT
COMMENTARY 
LITERATURE
ADH
ADH2
Adh319
AdhA
alcohol dehydrogenase
aldehyde reductase (NADPH/NADH)
-
-
-
-
HvADH2
HVO_B0071
NAD(P)+-dependent alcohol dehydrogenase
NAD(P)H-dependent aldehyde reductase
NADPH-dependent ADHA
NADPH-dependent alcohol dehydrogenase
PH0743
PhADH
RADH
retinal reductase
-
-
-
-
TsAdh319
Tsib_0319
VNG_2617G
YqhD
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REACTION
REACTION DIAGRAM
COMMENTARY
ORGANISM
UNIPROT
LITERATURE
a primary alcohol + NAD(P)+ = an aldehyde + NAD(P)H + H+
enzyme is stereospecific for the pro-R hydride of NADPH
-
a primary alcohol + NAD(P)+ = an aldehyde + NAD(P)H + H+
enzyme is stereospecific for the pro-R hydride of NADPH
-
a primary alcohol + NAD(P)+ = an aldehyde + NAD(P)H + H+
the defence-related alcohol dehydrogenase DRD-1 is an alcohol:NADP+ oxidoreductase with preference for various aromatic and aliphatic aldehydes
a primary alcohol + NAD(P)+ = an aldehyde + NAD(P)H + H+
the enzyme is an aldo-keto reductase
-
a primary alcohol + NAD(P)+ = an aldehyde + NAD(P)H + H+
the human pancreas protein 2 has a retinal reductase activity
a primary alcohol + NAD(P)+ = an aldehyde + NAD(P)H + H+
enzyme is stereospecific for the pro-R hydride of NADPH
-
-
a primary alcohol + NAD(P)+ = an aldehyde + NAD(P)H + H+
-
-
-
-
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REACTION TYPE
ORGANISM
UNIPROT
COMMENTARY
LITERATURE
oxidation
-
-
-
-
redox reaction
-
-
-
-
reduction
-
-
-
-
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SYSTEMATIC NAME
IUBMB Comments
alcohol:NAD(P)+ oxidoreductase
Reduces aliphatic aldehydes of carbon chain length from 2 to 14, with greatest activity on C4, C6 and C8 aldehydes; also reduces retinal to retinol.
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CAS REGISTRY NUMBER
COMMENTARY
37250-10-5
-
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SUBSTRATE
PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
LITERATURE
COMMENTARY
Reversibility
r=reversible
ir=irreversible
?=not specified
r=reversible
ir=irreversible
?=not specified
(1R)-1-hydroxy-1-phenylpropan-2-one + NADPH + H+
(1R)-1-phenylpropane-1,2-diol + NADP+
-
Substrates: -
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(2R)-2-hydroxy-1-(4-methoxyphenyl)propan-1-one + NADPH + H+
(2R)-1-(4-methoxyphenyl)propane-1,2-diol + NADP+
-
Substrates: -
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(2S)-2-hydroxy-1-(4-methoxyphenyl)propan-1-one + NADPH + H+
(2S)-1-(4-methoxyphenyl)propane-1,2-diol + NADP+
-
Substrates: -
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(4R,6S)-6-(chloromethyl)oxane-2,4-diol + NAD+
(4R,6S)-6-(chloromethyl)-4-hydroxyoxan-2-one + NADH + H+
-
Substrates: -
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(4R,6S)-6-(chloromethyl)oxane-2,4-diol + NADP+
(4R,6S)-6-(chloromethyl)-4-hydroxyoxan-2-one + NADPH + H+
-
Substrates: -
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(RS)-1-phenylethanol + NAD+
1-phenylethanone + NADH + H+
-
Substrates: 100% activity
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(RS)-1-phenylethanol + NADP+
1-phenylethanone + NADPH + H+
-
Substrates: 100% activity
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(S)-2-butanol + NADP+
butanone + NADPH
Substrates: 196% relative activity as compared to 2-propanol
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(S)-2-butanol + NADP+
butanone + NADPH + H+
Substrates: 196% of the activity with 2-propanol, 2fold preference for (S)-2-butanol over (RS)-2-butanol
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1,2-propanediol + NAD+
? + NADH + H+
Substrates: -
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1,3-butanediol + NADP+
? + NADPH + H+
Substrates: 91% relative activity as compared to 2-propanol
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1,3-propanediol + NAD+
? + NADH + H+
Substrates: -
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1-(2-bromophenyl)ethanol + NAD(P)+
1-(2-bromophenyl)ethanone + NAD(P)H + H+
-
Substrates: 11.3% activity compared to (RS)-1-phenylethanol
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1-(2-chlorophenyl)ethanol + NAD(P)+
1-(2-chlorophenyl)ethanone + NAD(P)H + H+
-
Substrates: 16.4% activity compared to (RS)-1-phenylethanol
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1-(3-bromophenyl)ethanol + NAD(P)+
1-(3-bromophenyl)ethanone + NAD(P)H + H+
-
Substrates: 315% activity compared to (RS)-1-phenylethanol
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1-(3-chlorophenyl)ethanol + NAD(P)+
1-(3-chlorophenyl)ethanone + NAD(P)H + H+
-
Substrates: 205% activity compared to (RS)-1-phenylethanol
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1-(4-bromophenyl)ethanol + NAD(P)+
1-(4-bromophenyl)ethanone + NAD(P)H + H+
-
Substrates: 167% activity compared to (RS)-1-phenylethanol
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1-(4-chlorophenyl)ethanone + NAD(P)+
1-(4-chlorophenyl)ethanone + NAD(P)H + H+
-
Substrates: 151% activity compared to (RS)-1-phenylethanol
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1-(4-fluorophenyl)ethanol + NAD(P)+
1-(4-fluorophenyl)ethanol + NAD(P)H + H+
-
Substrates: 119% activity compared to (RS)-1-phenylethanol
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1-(4-methylphenyl)ethanone + NAD(P)+
1-(4-methylphenyl)ethanol + NAD(P)H + H+
-
Substrates: 189% activity compared to (RS)-1-phenylethanol
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1-butanol + NAD(P)+
butanal + NAD(P)H + H+
-
Substrates: 2.3% activity compared to (RS)-1-phenylethanol
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1-butanol + NADP+
1-butanal + NADPH + H+
Substrates: -
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1-butanol + NADP+
butanal + NADPH
Substrates: 80% relative activity as compared to 2-propanol
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1-heptanol + NAD(P)+
heptanal + NAD(P)H + H+
-
Substrates: 3.3% activity compared to (RS)-1-phenylethanol
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1-hexanol + NAD(P)+
hexanal + NAD(P)H + H+
-
Substrates: 2.8% activity compared to (RS)-1-phenylethanol
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1-octanol + NAD(P)+
octanal + NAD(P)H + H+
-
Substrates: 2.3% activity compared to (RS)-1-phenylethanol
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1-octanol + NAD+
octanal + NADH + H+
Substrates: -
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1-pentanol + NAD(P)+
pentanal + NAD(P)H + H+
-
Substrates: 2.8% activity compared to (RS)-1-phenylethanol
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1-pentanol + NAD+
pentanal + NADH + H+
Substrates: -
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1-phenyl-1,2-ethanediol + NAD(P)+
?
-
Substrates: 3.4% activity compared to (RS)-1-phenylethanol
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1-phenyl-1-propanol + NAD(P)+
1-phenylpropionaldehyde + NAD(P)H + H+
-
Substrates: 13.1% activity compared to (RS)-1-phenylethanol
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1-phenyl-2-propanol + NAD(P)+
1-phenylpropan-2-one + NAD(P)H + H+
-
Substrates: 39.1% activity compared to (RS)-1-phenylethanol
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1-phenylethanol + NADP+
1-phenylethanone + NADPH + H+
Substrates: 35% of the activtiy with 1-propanol
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1-phenylethanol + NADP+
acetophenone + NADPH + H+
Substrates: 35% compared to activity with 1-propanol
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1-phenylmethanol + NADP+
benzaldehyde + NADPH + H+
Substrates: 180% relative activity as compared to 2-propanol
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1-propanol + NAD(P)+
propionaldehyde + NAD(P)H + H+
-
Substrates: 1.2% activity compared to (RS)-1-phenylethanol
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2,2,2-trifluoroacetophenone + NAD(P)H + H+
2,2,2-trifluoro-1-phenylethan-1-ol + NAD(P)+
-
Substrates: 180% activity compared to acetoin
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2-bromoacetophenone + NAD(P)H + H+
1-(2-bromophenyl)ethanone + NAD(P)+
-
Substrates: 8.7% activity compared to acetoin
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2-bromobenzaldehyde + NADPH
2-bromobenzyl alcohol + NADP+
-
Substrates: -
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2-bromobenzaldehyde + NADPH + H+
2-bromobenzyl alcohol + NADP+
-
Substrates: -
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2-butanol + NAD(P)+
butan-2-one + NAD(P)H + H+
-
Substrates: 22.3% activity compared to (RS)-1-phenylethanol
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2-butanol + NADP+
2-butanone + NADPH + H+
Substrates: 43% of the activity compared to ethanol
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2-chloro-1-phenylethanol + NAD(P)+
2-chloro-1-phenylethan-1-one + NAD(P)H + H+
-
Substrates: 0.3% activity compared to (RS)-1-phenylethanol
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2-cyclohexenol + NADP+
2-cyclohexenone + NADH + H+
-
Substrates: -
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2-cyclohexenone + NADH + H+
2-cyclohexenol + NADP+
-
Substrates: -
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2-fluorobenzaldehyde + NADPH + H+
2-fluorobenzyl alcohol + NADP+
-
Substrates: -
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2-heptanol + NAD(P)+
heptan-2-one + NAD(P)H + H+
-
Substrates: 61.6% activity compared to (RS)-1-phenylethanol
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2-hexanol + NAD(P)+
hexan-2-one + NAD(P)H + H+
-
Substrates: 38.7% activity compared to (RS)-1-phenylethanol
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2-hexanone + NAD(P)H + H+
hexan-2-ol + NAD(P)+
-
Substrates: 3.6% activity compared to acetoin
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2-hydroxy-2-methyl-1-phenylpropan-1-one + NADPH + H+
2-methyl-1-phenylpropan-1,2-diol + NADP+
-
Substrates: -
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?
2-hydroxy-3-methoxybenzaldehyde + NADPH + H+
2-hydroxy-3-methoxybenzyl alcohol + NADP+
Substrates: -
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?
2-methylbenzaldehyde + NADPH + H+
2-methylbenzyl alcohol + NADP+
-
Substrates: -
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2-octanol + NAD(P)+
octan-2-one + NAD(P)H + H+
-
Substrates: 45.8% activity compared to (RS)-1-phenylethanol
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2-pentanol + NAD(P)+
pentan-2-one + NAD(P)H + H+
-
Substrates: 30.2% activity compared to (RS)-1-phenylethanol
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2-pentanol + NADP+
2-pentanone + NADPH + H+
Substrates: 67% relative activity as compared to 2-propanol
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2-pentanol + NADP+
pentan-2-one + NADPH + H+
Substrates: 67% of the activity with 2-propanol
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2-phenylethanol + NAD(P)+
phenylacetaldehyde + NAD(P)H + H+
-
Substrates: 0.3% activity compared to (RS)-1-phenylethanol
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2-propanol + NAD(P)+
propan-2-one + NAD(P)H + H+
-
Substrates: 5.3% activity compared to (RS)-1-phenylethanol
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3,4-dimethoxybenzaldehyde + NADPH + H+
3,4-dimethoxybenzyl alcohol + NADP+
Substrates: -
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3-fluorobenzaldehyde + NADPH
3-fluorobenzyl alcohol + NADP+
-
Substrates: -
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3-methoxybenzaldehyde + NADPH + H+
3-methoxybenzyl alcohol + NADP+
-
Substrates: -
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?
3-methyl-2-pentanone + NADPH + H+
? + NADP+
Substrates: 13% relative activity as compared to pyruvaldehyde
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3-methylbenzaldehyde + NADPH + H+
3-methylbenzyl alcohol + NADP+
-
Substrates: -
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3-methylbutanal + NADP+
? + NADPH + H+
Substrates: about% of the activity with 1-butanol
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3-methylcyclohexanone + NADH + H+
3-methylcyclohexanol + NAD+
-
Substrates: -
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4-bromobenzaldehyde + NADPH + H+
4-bromobenzyl alcohol + NADP+
-
Substrates: -
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4-fluorobenzaldehyde + NADPH + H+
4-fluorobenzyl alcohol + NADP+
-
Substrates: -
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4-methylbenzaldehyde + NADPH + H+
4-methylbenzyl alcohol + NADP+
-
Substrates: -
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4-methylnitrosamino-1-(3-pyridyl)-1-butanone + NADPH + H+
?
-
Substrates: -
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4-methylpentan-2-one + NADPH + H+
4-methylpentan-2-ol + NADP+
-
Substrates: -
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4-phenyl-2-butanone + NADH + H+
4-phenyl-2-butanol + NAD+
-
Substrates: -
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acetoin + NAD(P)+
butan-2,3-dione + NAD(P)H + H+
-
Substrates: 100% activity
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acetoin + NAD(P)H + H+
2,3-butanediol + NAD(P)+
-
Substrates: 4.5% activity compared to (RS)-1-phenylethanol
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acetoin + NADPH + H+
?
-
Substrates: 1.9% activity compared to 3-hydroxypropionaldehyde
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acetone + NAD(P)H + H+
propan-2-ol + NAD(P)+
-
Substrates: 4.1% activity compared to acetoin
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acetophenone + NADH + H+
1-phenylethan-1-ol + NAD+
-
Substrates: -
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acrolein + NADPH + H+
prop-2-en-1-ol + NADP+
-
Substrates: 41.8% activity compared to 3-hydroxypropionaldehyde
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all-trans-retinal + NADPH + H+
all-trans-retinol + NADP+
-
Substrates: -
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all-trans-retinol + NADP+
all-trans-retinal + NADPH + H+
Substrates: -
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benzaldehyde + NAD(P)H
benzyl alcohol + NAD(P)+
-
Substrates: -
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benzaldehyde + NADPH + H+
benzyl alcohol + NADP+
Substrates: -
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benzylalcohol + NAD+
benzaldehyde + NADH + H+
Substrates: -
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butan-1,4-diol + NADP+
butandialdehyde + NADPH
-
Substrates: 29% of activity with hexan-1-ol
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butanal + NADPH + H+
1-butanol + NAD(P)+
Substrates: 44% activity compared to pentanal
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cinnamaldehyde + NADPH + H+
cinnamyl alcohol + NADP+
Substrates: -
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cis-4-cyclopentene-1,3-diol + NADP+
(R)-4-hydroxy-2-cyclopentenone + NADPH + H+
-
Substrates: -
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cis-4-heptenal + NAD(P)+
cis-4-heptenol + NAD(P)H
-
Substrates: -
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cis-hex-3-en-1-ol + NADP+
cis-hex-3-en-1-al + NADPH
-
Substrates: 18.7% of activity with hexan-1ol
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cyclohexanol + NAD(P)+
cyclohexanone + NAD(P)H + H+
-
Substrates: 52.3% activity compared to (RS)-1-phenylethanol
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cyclohexanol + NAD+
cyclohexanone + NADH + H+
Substrates: -
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cyclohexanone + NAD(P)H + H+
cyclohexanol + NAD(P)+
-
Substrates: 19.1% activity compared to acetoin
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D-arabinose + NAD(P)+
?
-
Substrates: 21.4% activity compared to (RS)-1-phenylethanol
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D-arabinose + NADP+
? + NADPH + H+
Substrates: 200% relative activity as compared to 2-propanol
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D-arabinose + NADP+
D-arabitol + NADPH + H+
Substrates: 200% of the activity with 2-propanol. D-arabinose is preferred over L-arabinose
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D-mannose + NADP+
? + NADPH + H+
Substrates: 48% relative activity as compared to 2-propanol
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D-ribose + NADP+
? + NADPH + H+
Substrates: 35% relative activity as compared to 2-propanol
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decan-1-ol + NADP+
decanal + NADPH
-
Substrates: decrease in enzyme activity with increase in chain length
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dihydroxyacetone + NAD(P)H + H+
?
-
Substrates: 34.8% activity compared to acetoin
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dodecan-1-ol + NADP+
dodecanal + NADPH
-
Substrates: decrease in enzyme activity with increase in chain length
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ethanol + NAD(P)+
acetaldehyde + NAD(P)H + H+
-
Substrates: 0.5% activity compared to (RS)-1-phenylethanol
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ethyl acetoacetate + NADPH + H+
? + NADP+
-
Substrates: -
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ethyl pyruvate + NAD(P)H + H+
?
-
Substrates: 294% activity compared to acetoin
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farnesyl aldehyde + NAD(P)H
farnesol + NAD(P)+
-
Substrates: -
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furan-2-carbaldehyde + NADPH + H+
(furan-2-yl)methanol + NADP+
-
Substrates: -
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furfural + NADPH + H+
(furan-2-yl)methanol + NAD(P)+
Substrates: 5% activity compared to pentanal
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glycerol + NADP+
glyceraldehyde + NADPH + H+
Substrates: 16% relative activity as compared to 2-propanol
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glycoaldehyde + NADPH + H+
?
Substrates: 5% activity compared to pentanal
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glyoxylic acid + NADPH + H+
? + NADP+
Substrates: 36% relative activity as compared to pyruvaldehyde
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heptan-1-ol + NADP+
heptanal + NADPH
-
Substrates: -
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heptanal + NADPH + H+
1-heptanol + NAD(P)+
Substrates: 56% activity compared to pentanal
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hexanal + NAD(P)H + H+
hexan-1-ol + NAD(P)+
-
Substrates: 12.9% activity compared to acetoin
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hexanal + NADPH + H+
1-hexanol + NAD(P)+
Substrates: 62% activity compared to pentanal
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hydrocinnamaldehyde + NADPH + H+
hydrocinnamyl alcohol + NADP+
Substrates: -
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isoamyl alcohol + NADP+
? + NADPH + H+
Substrates: about 80% of the activity with 1-butanol
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L-arabinose + NAD(P)+
?
-
Substrates: 5.2% activity compared to (RS)-1-phenylethanol
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L-arabinose + NADP+
? + NADPH + H+
Substrates: 17% relative activity as compared to 2-propanol
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linolenyl aldehyde + NAD(P)H
linolenol + NAD(P)+
-
Substrates: -
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linoleyl aldehyde + NAD(P)H
linoleol + NAD(P)+
-
Substrates: -
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mannitol + NADP+
D-mannose + NADPH
-
Substrates: 6.5% of activity with hexan-1-ol
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meso-2,3-butanediol + NAD+
?
-
Substrates: 272% activity compared to (RS)-1-phenylethanol
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meso-2,3-butanediol + NADP+
?
-
Substrates: 272% activity compared to (RS)-1-phenylethanol
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methanol + NAD(P)+
formaldehyde + NAD(P)H + H+
-
Substrates: 0.2% activity compared to (RS)-1-phenylethanol
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methyl benzoylformate + NAD(P)H + H+
?
-
Substrates: 67% activity compared to acetoin
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methylglyoxal + NADPH + H+
2-hydroxy-propanal + NADP+
-
Substrates: -
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methylglyoxal + NADPH + H+
?
Substrates: 29% activity compared to pentanal
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octan-1-ol + NADP+
octanal + NADPH
-
Substrates: decrease in enzyme activity with increase in chain length
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r
octan-1-ol + NADP+
octanal + NADPH + H+
-
Substrates: -
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r
octanal + NADPH + H+
1-octanol + NAD(P)+
Substrates: 55% activity compared to pentanal
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pentanal + NADPH + H+
1-pentanol + NAD(P)+
Substrates: 100% activity
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phenylacetaldehyde + NAD(P)H + H+
2-phenylethan-1-ol + NAD(P)+
-
Substrates: 18.6% activity compared to acetoin
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propanal + NADPH + H+
1-propanol + NAD(P)+
Substrates: 14% activity compared to pentanal
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pyridine-2-carbaldehyde + NADPH + H+
(pyridin-2-yl)methanol + NADP+
-
Substrates: -
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pyruvaldehyde + NADPH + H+
? + NADP+
Substrates: -
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pyruvic aldehyde + NAD(P)H + H+
?
-
Substrates: 328% activity compared to acetoin
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rac-1-nonen-4-ol + NADP+
(S)-1-nonen-4-ol + 1-nonen-4-one + NADPH + H+
-
Substrates: -
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rac-1-phenylethanol + NAD(P)+
acetophenone + (R)-1-phenylethanol + NAD(P)H + H+
-
Substrates: -
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rac-1-phenylethanol + NADP+
(R)-1-phenylethanol + (S)-1-phenylethanol + NADPH + H+
-
Substrates: -
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ribitol + NADP+
D-ribose + NADPH
-
Substrates: 4% of activity with hexan-1-ol
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r
salicylaldehye + NADPH + H+
salicylalcohol + NADP+
Substrates: -
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tetradecanal + NAD(P)H
tetradecan-1-ol + NAD(P)+
-
Substrates: -
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trans-2,cis-6-nonadienal + NAD