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Information on EC 1.14.19.64 - (S)-stylopine synthase

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IUBMB Comments
A heme-thiolate enzyme (P-450) catalysing an oxidative reaction that does not incorporate oxygen into the product. Forms the second methylenedioxy bridge of the protoberberine alkaloid stylopine from oxidative ring closure of adjacent phenolic and methoxy groups of cheilanthifoline.
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Word Map
The enzyme appears in viruses and cellular organisms
Synonyms
stylopine synthase, cyp719a2, cyp719a3, methylenedioxy bridge-forming enzyme, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
(S)-cheilanthifoline + [reduced NADPH-hemoprotein reductase] + O2 = (S)-stylopine + [oxidized NADPH-hemoprotein reductase] + 2 H2O
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